CONTROL OF MOLECULAR ARRANGEMENT IN FUNCTIONAL ORGANIC FILMS USING BIAS-VOLTAGE APPLIED LBTECHNIQUE

使用偏压 LB 技术控制功能有机薄膜中的分子排列

• 批准号: 06650354
• 负责人: KUDO Kazuhiro
• 金额: $ 1.28万
• 依托单位: CHIBA UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (C)
• 财政年份: 1994
• 资助国家: 日本
• 起止时间: 1994 至 1995
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-06650354/
• 关键词: Organic thin films; Adsorption LB technigue; Bias-applied LB technique; Molecular adsorption; Molecular arrangement; TCNQ; Triphenylmethane dyes; 電位印加LB法

We have investigated organic thin films fabricated by a baisvoltage applied Langmuir-Blodgett (LB) method. Main results are summarized below.1) A remarkable efect of bias voltage is observed in adsorbption LB films.2) The bias voltage applied to the substrate affects the interaction between the molecules and substrate.3) The quantity of adsobing dyes and spreading molecules in the LB films can be controlled by using this technique.4) The controllability of the charge transfer complex formation is also suggested.These results obtained here demonstrate that the bias-voltage applied LB technique is useful to control the molecular arragement in functional organic thin films.

我们研究了通过朗缪尔-布洛杰特 (LB) 方法应用拜电压制备的有机薄膜。主要结果总结如下：1）在吸附LB膜中观察到偏压的显着影响。2）施加到基底上的偏压影响分子与基底之间的相互作用。3）使用该技术可以控制LB膜中吸附染料和铺展分子的数量。4）电荷转移络合物形成的可控性 这里获得的这些结果表明，施加偏压的 LB 技术可用于控制功能有机薄膜中的分子排列。

项目成果

板寺一彦: "電圧印加LB法によるドナー性分子吸着CnTCNQLB膜の作製" 第56回応用物理学会学術講演会講演予稿集. 3. 965 (1995)

Kazuhiko Itadera：“通过电压施加LB法制备吸附供体分子的CnTCNQLB薄膜”日本应用物理学会第56届年会论文集3. 965（1995）。

Kazuhiro Kudo: "Optical and Electrical Evaluation of Adsorption Langmuir-Blodgett Films of C18TCNQ/TMPD and C18TCNQ/PPD" Synthetic Metals. 71. 2059-2060 (1995)

Kazuhiro Kudo：“C18TCNQ/TMPD 和 C18TCNQ/PPD 吸附 Langmuir-Blodgett 薄膜的光学和电学评估”合成金属。

Kazuhiko Itadera: "Fabrication of Dye-Adsorbed Merocyanine Thin Films by a Bias Voltage Langmuir Blodgett Technique" Japanese Journal Applied Physics. 34. 4907-4909 (1995)

Kazuhiko Itadera：“通过偏置电压 Langmuir Blodgett 技术制造染料吸附的部花青薄膜”，日本应用物理学杂志。

Kazuhiro Kudo: "Control of Charge-Transfer Complex Formation by a Bias Voltage Applied LB Technique" Technical Report of IEICE. OME95-64. 47-52 (1995)

Kazuhiro Kudo：“通过偏压应用 LB 技术控制电荷转移复合物的形成”IEICE 的技术报告。

Kazuhiro Kudo: "Optical and Electrical Evaluation of Molecular Adsorption Langmuir-Blodgett Films of C18TCNQ/TMPD and C18TCNQ/PPD" Synthetic Metals. 71. 2059-2060 (1995)

Kazuhiro Kudo：“C18TCNQ/TMPD 和 C18TCNQ/PPD 分子吸附 Langmuir-Blodgett 薄膜的光学和电学评估”合成金属。