Synthesis of Coordination Complexes with Mesoscopic Size and Control of their Magnetic Properties

我们的目标是开发新型的功能配位纳米团簇。我们已经成功地合成了几种单分子磁体。它们是具有轮状结构的十二核MnFe络合物、具有拱形结构的四核MnFe络合物和具有方形结构的四核NiFe络合物。此外，我们还成功地合成了一维光可调谐的同位手性钼铜络合物。这些材料可用作未来高密度记录设备的部件。

We aimed at developing novel functional coordination nano-clusters. We have succeeded in synthesizing several single molecule magnets. They are dodecanuclear MnFe complexes with wheel structure, tetranuclear MnFe complex with arch structure, and tetranuclear NiFe complex with square structure. Moreover, we have succeeded in synthesizing a photo-tunable one-dimensional homo-chiral MoCu complex. These materials can be used as components of future high density recording devises.