Base-Promoted Oxidative PCET Remote Functionalization (B06)

该项目旨在提高对（氧化）多位点质子耦合电子转移反应（MS PCET）中碱、oh -底物和光催化氧化剂的关系的理解。鉴定这些三元组合中的关键相互作用，这是与光谱学合作所追求的，以及调制这些组合效应以促进PCET，应该允许在最好温和的条件下产生烷氧基自由基。从合成的角度来看，这反过来又可以实现非活化醇的多用途光催化远程功能化，特别是在与多催化设置的兼容性方面。

The project aims at the improved understanding of the association of base, OH-substrate and photocatalytic oxidant in (oxidative) multisite proton-coupled electron transfer reactions (MS PCET). The identification of the critical interactions within these ternary assemblies, which is sought after in collaboration with spectroscopy, and the modulation of these assembly effects to facilitate PCET should allow for alkoxy radical generation under preferably mild conditions. From a synthetic point of view this in turn should enable versatile photocatalytic remote functionalization of non-activated alcohols, especially with respect to compatibility with multicatalytic settings.