Coordination Funds

离散金属配合物电子激发态势能面的设计对于揭示和利用这类化合物的光物理和光化学至关重要。优先方案的目的是为新的功能性光敏金属络合物开发合理的设计概念。在该计划的核心是光诱导金属为中心的过程和金属络合物的电子激发态的动力学的基本理解，包括： 开发基于丰富金属的分子发射体和敏化剂，以取代稀有和贵金属中心， 理解和设计金属络合物的电子激发态，用于诊断，成像，治疗和分子传感器的潜在应用， 开发电子激发金属络合物的概念性新反应模式， 提供基于高度还原或氧化电子激发金属络合物的新物质类别的访问， 光诱导多电子和多质子过程的发展; 了解动态环境对软基质中金属络合物激发态性质的影响。该计划受益于超快光谱（IR到X射线能量）领域的补充新发展和新的理论发展。该计划包括以下四个部分： 新型金属基发光体 新型（地球丰富）金属基光敏剂 金属基系统中能量传递、多电子和多质子过程的基本问题及 过渡金属络合物中的光诱导键活化。项目联盟包括以下三个主题中至少两个主题的研究活动： 新型光活性金属配合物的合成和基态表征， 激发态性质的光谱研究，特别是使用时间分辨方法（fs - ms，IR -X射线）和· 激发态性质的理论研究。协调项目支持在该计划中工作的科学家的整合，沟通和信息交流。该计划PP 2102将继续使用不同的工具来促进合作和博士生的培训：与PP中的所有团队的进度报告会议和与国内和国际专家的专题研讨会，以更好地融入国际网络。

The design of the potential energy landscape of electronically excited states in discrete metal complexes is of utmost importance for unveiling and exploiting the photophysics and photochemistry of this class of compounds. The Priority Programme aims at the development of rational design concepts for new functional photoactive metal complexes. At the core of the programme is the fundamental understanding of photoinduced metal-centred processes and the dynamics of electronically excited states of metal complexes, including:• development of molecular emitters and sensitizers based on abundant metals to replace rare and precious metal centres,• understanding and design of electronically excited states of metal complexes for potential applications in diagnostics, imaging, therapy, and molecule-based sensors,• development of conceptually new reactivity patterns of electronically excited metal complexes,• providing access to new substance classes based on highly reducing or oxidizing electronically excited metal complexes,• development of photoinduced multielectron and multiproton processes and• understanding of dynamic environmental effects on the excited state properties of metal complexes in soft matrices.The programme benefits from complementary new developments in the field of ultrafast spectroscopy (IR to X-ray energies) and from new theoretical developments.The programme comprises the following four subsections:• Novel Metal-based Luminophores,• Novel (Earth-abundant) Metal-based Photosensitizers,• Fundamental Aspects of Energy Transfer, Multielectron and Multiproton Processes in Metal-based Systems and• Photoinduced Bond Activation in Transition Metal Complexes.The project consortia comprise research activities covering at least two of the three following topics:• synthesis and ground-state characterisation of new photoactive metal complexes,• spectroscopic investigations of excited state properties, especially using time-resolved methods(fs – ms, IR – X-ray) and• theoretical investigations on excited state properties.The coordination project supports the integration, communication, and information exchange of scientists working in the program.The program PP 2102 will continue to use different tools to facilitate cooperation and training of PhD students: Progress report meetings with all teams in the PP and topical workshops with national and international experts for better integration in international networks.