Control of Super-Hierarchical Helical Structures of Next-Generation Conjugated Polymers and Their Innovative Functions

下一代共轭聚合物超多级螺旋结构的控制及其创新功能

• 批准号: 17067002
• 负责人: AKAGI Kazuo
• 金额: $ 21.38万
• 依托单位: Kyoto University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research on Priority Areas
• 财政年份: 2005
• 资助国家: 日本
• 起止时间: 2005 至 2009
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-17067002/
• 关键词: 共役ポリマー; 階層制御; 機能制御; ヘリカルポリアセチレン; キラル液晶場; らせん構造; キラル発光; キラルドーパント; 高分子合成; 高分子構造・物性; 超階層構造; 電子・電気材料; 光・磁気機能; 合成金属; 共役ポリマー科学; 階層構造; 共役高分子; 若手育成; 非線形現象

The present research area has aimed to explore profound potentialities of conjugated polymers and to extract innovative electronic, magnetic and optical functions that should give rise to the next-generation materials. The project has focused on (i) synthesis of novel and fruitful conjugated polymers by means of sophisticated designs for molecules and chemical reactions, and (ii) super-hierarchical control covering primary to higher order structures, and morphological control of self-organized assemblies and complexes, and (iii) precise evaluation of physical properties and investigation of intrinsic functions by virtue of well defined multi-layered structures. Through rigorous achievement of the project, we have fostered and cultivated the scientific field of conjugated polymers.

目前的研究领域旨在探索共轭聚合物的巨大潜力，并提取创新的电子，磁性和光学功能，这些功能应该会产生下一代材料。该项目的重点是（i）通过复杂的分子和化学反应设计合成新颖和富有成效的共轭聚合物，（ii）覆盖初级到高级结构的超层次控制，以及自组织组装和复合物的形态控制，（iii）凭借明确的多层结构精确评估物理性能和研究内在功能。通过严格的项目成果，我们培育和培养了共轭聚合物的科学领域。

项目成果

Suppression of the magneto resistance in high electric fields of polyacetylene nanofibers

• DOI: 10.1016/j.synthmet.2010.04.014
• 发表时间: 2010-06-01
• 期刊: SYNTHETIC METALS
• 影响因子: 4.4
• 作者: Choi, A.;Lee, H. J.;Park, Y. W.
• 通讯作者: Park, Y. W.

Chiral 1-Methylpropargyl Alcohol: A Simple and Powerful Helical Source for Substituted Polyacetylenes

• DOI: 10.1021/ma0629642
• 发表时间: 2007-02
• 期刊: Macromolecules
• 影响因子: 5.5
• 作者: Yuji Suzuki;M. Shiotsuki;F. Sanda;T. Masuda

Chemical and electrochemical oxidation of thiophene-pyridine and thiophene-pyrimidine co-oligomers in solutions.

• DOI: 10.1021/jp071614u
• 发表时间: 2007-06
• 期刊: The journal of physical chemistry. B
• 作者: A. Kumagai;Hiroki Fukumoto;Takakazu Yamamoto

A comparative study of Al and LiF:Al interfaces with poly (3-hexylthiophene) using bias dependent photoluminescence technique

• DOI: 10.1016/j.orgel.2008.05.012
• 发表时间: 2008-10
• 期刊: Organic Electronics
• 影响因子: 3.2
• 作者: Vipul Singh;A. Thakur;S. Pandey;W. Takashima;K. Kaneto

Effect of diene ligands in the rhodium-catalyzed polymerization of phenylacetylene

• DOI: 10.1021/ma061689g
• 发表时间: 2006-11
• 期刊: Macromolecules
• 影响因子: 5.5
• 作者: Irfan Saeed;M. Shiotsuki;T. Masuda