Nonlinear Infrared Short-Time Spectroscopy for the Characterization of Fluorine-Specific Interactions: Structure, Dynamics and Catalytic Determinants of H∙∙∙F-Networks on Fluorido Complexes and Metallo-peptides (A09*)

在A9N|Horch项目中，使用超快和非线性2D红外光谱和量子化学计算来阐明和量化氟特定相互作用的结构和动力学方面。重点放在催化金属中心配位范围内的相互作用，特别是涉及含氟反应物或含氟配体体系的氢键。此外，还阐明了多肽与含氟氨基酸金属络合物中的氟专一性相互作用。

In project A9N|Horch, ultrafast and nonlinear 2D infrared spectroscopy and quantum chemical calculations are used to elucidate and quantify structural and dynamic aspects of Fluorine-Specific interactions. The focus is on interactions in the coordination sphere of catalytic metal centers, particularly hydrogen bonds involving fluo-rine-containing reactants or fluorinated ligand systems. Furthermore, Fluorine-Specific interactions in metal complexes of peptides with fluorinated amino acids are elucidated.