Synthesis of Functional Inclusion Compounds for Molecular Composite Materials

分子复合材料功能性包合物的合成

• 批准号: 61550678
• 负责人: MIYATA Mikiji
• 金额: $ 1.28万
• 依托单位: Osaka University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (C)
• 财政年份: 1986
• 资助国家: 日本
• 起止时间: 1986 至 1988
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-61550678/
• 关键词: Inclusion Compounds; Inclusion Polymerization; Molecular Composite Materials; Polydiacetylene; Polyacetylene; Deoxycholic Acid; Propagating Radicals; フェロセン; 共役系高分子; コール酸; ホスト・ゲスト; チャンネル; 電子スピン共鳴分光法; ラジカル; 電導性; 電気的性質; 脱ハロゲン化水素

We studied functional inclusion compounds for molecular composite materials. We used deoxycholic acid and apocholic acid as the traditional hosts, as well as cholic acid and its derivatives as the new one. The guest components were conjugated polymers such as polydiacetylene and polyacetylene, and an organometallic compound such as ferrocene. The results are summarized as follows:1. We prepared the inclusion compounds of the hosts with polydiacetylene by an inclusion polymerization method. The polymerization proceeded via 1,4-addition preferentially in the one-dimensional spaces, channels.2. We prepared a precursor polymer of polyacetylene, that is, poly(1-chlorobutadiene) by the same method, since the reaction occurred highly selectively via 1,4-trans, head-to-tail addition in the channels. The dehydrochlorination of the polymer proceeded smoothly both in case of the precursor and the inclusion compounds.3. The electric conductivities of the conjugated polymers were not so high, but increased greatly on the iodine doping. ESR studies showed high electron spin densities of the polymers.4. We observed the ESR spectra of the propagating radicals in case of the inculsion polymerization of 1-chlorobutadiene in the channels. The molecular weight of the polymers increased with increasing reaction time in the initial stage.

研究了分子复合材料中的功能包合物。我们用去氧胆酸和去氧胆酸作为传统的宿主，用胆酸及其衍生物作为新的宿主。客体组分是共轭聚合物如聚丁二炔和聚乙炔，以及有机金属化合物如二茂铁。主要研究结果如下：1.采用包合聚合法制备了主体与聚丁二炔的包合物。聚合反应优先在一维空间通道中通过1，4-加成进行.我们通过相同的方法制备了聚乙炔的前体聚合物，即聚（1-氯丁二烯），因为反应通过通道中的1，4-反式，头-尾加成高度选择性地发生。无论是前驱体还是包结物，聚合物的脱氯化氢反应都顺利进行.共轭聚合物的电导率并不高，但碘掺杂后电导率大大提高。ESR研究表明聚合物具有较高的电子自旋密度.观察了1-氯丁二烯在孔道内引发聚合时增长自由基的ESR谱。聚合物的分子量在初始阶段随反应时间的增加而增加。

项目成果

Kunio Miki: "Structure of a 2:1 Complex between Deoxycholic Acid and Ferrocene" Journal of Chemical Society, Chemical Communication. 545-546 (1987)

Kunio Miki：“脱氧胆酸和二茂铁之间的 2:1 复合物的结构”化学学会杂志，化学通讯。

堤宏守: Die Makro molekulare Chemie:Rapid Communications. (1987)

Hiromori Tsutsumi：Die Makro molecular Chemie：Rapid Communications (1987)。

Hiromori Tsutsumi: "Inclusion Compounds of Poly(1,3-butadiyne) in Deoxycholic Acid and Apocholic Acid Canals: Synthesis and Characterization" Journal of Polymer Science, Polymer Chemistry. 25. 3079-3087 (1987)

Hiromori Tsutsumi：“脱氧胆酸和阿波胆酸通道中聚（1,3-丁二炔）的包合物：合成和表征”高分子科学杂志，高分子化学。

宮田幹二: Journal of Inclusion Phenomena. (1987)

宫田宽治：包容现象杂志（1987）。

三木邦夫: Journal of Chemical Society,Chemical Communication. 545-546 (1987)

Kunio Miki：《化学学会杂志》，《化学通讯》545-546 (1987)。