Developments of Composite and Bondiing Materials Prepared by High Pressure Process

高压复合材料和粘接材料的研究进展

• 批准号: 05555168
• 负责人: FUKUNAGA Osamu
• 金额: $ 6.02万
• 依托单位: Tokyo Institute of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Developmental Scientific Research (B)
• 财政年份: 1993
• 资助国家: 日本
• 起止时间: 1993 至 1995
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-05555168/
• 关键词: pressure effect; macro composite; copper oxide superconductors; diamond dispersed composite; TiC dispersed diamond; 炭化チタン分散ダイヤモンド; 超高圧; コンポジット材料; ダイヤモンド系の液相焼結; 超電導酸化物; SiC-ダイヤモンド系; Sr_2CuO_3rs系; 圧力コンポジット; 超伝導酸化物; CBN-ガラス系; ZnS-ダイヤモンド系; cBN

This study was carried out to develop new composite materials which show characteristic properties in both microscopic and macroscopic levels focusing on the high pressure effect to the materials. The composites in this study is defined more broader sense containing amorphous hydroxide compounds prepared at high pressure which forming a microscopic composite by doping water into the structure at high pressure. When high pressure stable diamond or cubic BN particles were dispersed in the matrix, we can prepare macro-composite.Micro-composite studied were Sr-Cu-O and La-Sr-Cu-O compounds. These compounds showed high pressure phase transformation and only oxygen doped high pressure phases showed superconductivity. We studied pressure, temperature and composition relationship and doping effect of oxygen to realize superconducting state.Diamond and cBN dispersed sintered composite were studied as macro-composite. Evaluation as cutting tool performance was carried out using hardened tool steel work. New TiC dispersed diamond composite was developed.

本研究的目的是开发新的复合材料，这些材料在微观和宏观层面上都表现出特征性的性能，重点是高压对材料的影响。本研究中的复合材料被定义为更广义的复合材料，其包含在高压下制备的无定形氢氧化物化合物，其通过在高压下将水掺杂到结构中而形成微观复合材料。当高压稳定的金刚石或立方氮化硼颗粒分散在基体中时，可以制备宏观复合材料，所研究的微观复合材料为Sr-Cu-O和La-Sr-Cu-O化合物。这些化合物表现出高压相变，只有氧掺杂的高压相表现出超导电性。研究了实现超导态的压力、温度与成分的关系以及氧的掺杂效应，并将金刚石和立方氮化硼弥散烧结复合材料作为宏观复合材料进行了研究。使用硬化工具钢工件进行切削工具性能评价。研制了一种新型TiC弥散金刚石复合材料。

项目成果

Xiao-Zheng Rong and O.Fukunaga: "Cubic BN-WC-Co Composite Sintered at High Pressures and High Temperatures" Diamond Films and Technology. 3 [2]. 65-75 (1993)

荣晓正和 O.Fukunaga：“高压高温下烧结的立方 BN-WC-Co 复合材料”金刚石薄膜和技术。

S.Nakano, H.Ikawa and O.Fukunaga: "Synthesis of cubic boron nitride using Li_3BN_2, Sr_3B_2N_4 and Ca_3B_2N_4 as solvent-catalysts" Diamond and Related Materials. 3. 75-82 (1993)

S.Nakano、H.Ikawa 和 O.Fukunaga：“使用 Li_3BN_2、Sr_3B_2N_4 和 Ca_3B_2N_4 作为溶剂催化剂合成立方氮化硼”金刚石和相关材料。

福長 脩: "材料としてのダイヤモンド" 材料科学. 32. 7-11 (1995)

Osamu Fukunaga：“金刚石作为材料”材料科学 32. 7-11 (1995)。

S.Nakano, H.Ikawa and O.Fukunaga: "High pressure reactions and formation mechanism of cubic BN in the system BN-Mg_3N_2" Diamond and Related Materials. 2. 1168-1174 (1993)

S.Nakano、H.Ikawa 和 O.Fukunaga：“BN-Mg_3N_2 体系中立方 BN 的高压反应和形成机制”金刚石和相关材料。

H.Fujioka,N.Ohashi,T.Tsurumi,O.Fukunaga and S.Nakano: "Synthesis of Cubic Boron Nicride by CaLiBN2 Catalyst at HT/HP" Advances in New Diamond Science and Technology,S.Saito et al.551-554 (1994)

H.Fujioka、N.Ohashi、T.Tsurumi、O.Fukunaga 和 S.Nakano：“CaLiBN2 催化剂在高温/高压下合成立方氮化硼”新金刚石科学技术的进展，S.Saito 等人 551-