The Study on the Development of New Types of Lithium Battery Electrolyte Solution with Highly Lipophilic Fluorinated Organic Lithium Salts

高亲油性含氟有机锂盐新型锂电池电解液的开发研究

基本信息

  • 批准号:
    05555241
  • 负责人:
  • 金额:
    $ 1.41万
  • 依托单位:
  • 依托单位国家:
    日本
  • 项目类别:
    Grant-in-Aid for Developmental Scientific Research (B)
  • 财政年份:
    1993
  • 资助国家:
    日本
  • 起止时间:
    1993 至 1994
  • 项目状态:
    已结题

项目摘要

This is a fundamental research to develope the new types of lithium batteries with high power and energy density. For molecular designing of fluorinated organic lithium salts as lithium battery electrolytes and for evaluating the battery properties of the electrolytes for practical utilization, the following works were done in two years.1.Synthetic procedures for the following lithium salts of polyfluorinated organic anions with different chain lengths and structures for electrolytes for lithium battery were developed : polyfluoroalkylsulfonyl-substituted amides, polyfluoroalkylsulfonyl-substituted methanides, polyfluoroalkyl-substituted tetraphenylborates.2.The effect of the structure of counter anions on the conductivity of the lithium salts wass experimentally investigated.3.Molecular orbital method calculations on the frontier orbital HOMO energy levels, bulkiness, lipophilicity, and ionic radii of the counter anions were done to investigate the relashionship between the stability and conductivity of the lithium salts and the stereoelectronic charactors of the polyfluorinated organic anions.4.Continuous study to evaluate the speciality of the lithium battery with various electrolytes are under progress.
这是开发新型高功率、高能量密度锂电池的基础性研究。为了对含氟有机锂盐锂电池电解质进行分子设计,并对电解质的电池性能进行评价,以供实际应用,本论文在两年内完成了以下工作:1.合成了以下不同链长和结构的多氟有机阴离子锂盐锂电池电解质:多氟烷基磺酰基取代的酰胺,多氟烷基磺酰基取代的甲烷化物,多氟烷基3.用分子轨道方法计算了四苯基硼酸锂盐的电导率,并讨论了它们的结构对电导率的影响通过计算前线轨道HOMO能级、体积、亲脂性和离子半径,研究了锂盐的稳定性和导电性与多氟有机阴离子的立体电子性质之间的关系。4.对不同电解质锂电池性能的评价正在进行中。

项目成果

期刊论文数量(13)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
Fusaji Kita,Akira Kawakami, Takaaki Sonoda, Hiroshi Kobayashi: "On the New Fluorinated Organic Lithium Salts for Lithium Batteries," Proceedings of 183rd Electrochemical Society. 93-23,. 321-333 (1993)
Fusaji Kita、Akira Kawakami、Takaaki Sonoda、Hiroshi Kobayashi:“关于锂电池的新型氟化有机锂盐”,第 183 届电化学会论文集。
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    0
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Hiroshi Kobayashi, Fusaji Kita, Akihisa Nagira, Nie Jin, Akinari Sonoda, and Takaaki Sonoda: "The solution Chemistry of TFPB Salts : The Electrophilicity of Naked Alkali Metal Ions" The Reports of Institute of Advanced Material Study, Kyushu University. V
Hiroshi Kobayashi、Fusaji Kita、Akihisa Nagira、Nie Jin、Akinari Sonoda 和 Takaaki Sonoda:“TFPB 盐的溶液化学:裸碱金属离子的亲电性”九州大学先进材料研究所的报告。
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    0
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Fusaji Kita, Akira Kawakami, Takaaki Sonoda, and Hiroshi Kobayashi: "On the New Fluorinated Organic Lithium Salts for Lithium Batteries" Proceedings of 183rd Electrochemical Society. Vol.93-23. 321-333 (1993)
Fusaji Kita、Akira Kawakami、Takaaki Sonoda 和 Hiroshi Kobayashi:“关于用于锂电池的新型氟化有机锂盐”第 183 届电化学会论文集。
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  • 影响因子:
    0
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  • 通讯作者:
Jin Nie, Hiroshi Kobayashi: "Hans-Dieter Meyer zu Duttingdorf, and Takaaki Sonoda, Synthesis and Properties of Poly ((perfluoroalkyl) sulfonyl) -amides and Methanude Ions as New Types of Anionic Phase-Transfer Catalysts in Azo Coupling Reaction" The Repor
Jin Nie、Hiroshi Kobayashi:“Hans-Dieter Meyer zu Duttingdorf 和 Takaaki Sonoda,聚(全氟烷基)磺酰基)酰胺和甲烷离子作为偶氮偶联反应中新型阴离子相转移催化剂的合成和性能”报告
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    0
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Hiroshi Kobayashi, Jin Nie, and Takaaki Sonoda: "Metal Bis ((perfluoroalkyl) sulfonyl) amides as Novel Lewis Acid Catalysts in Diels-Alder Reaction" Chemistry Letterrs. Vol.1995, (in press). (1995)
Hiroshi Kobayashi、Jin Nie 和 Takaaki Sonoda:“金属双((全氟烷基)磺酰基)酰胺作为狄尔斯-阿尔德反应中的新型路易斯酸催化剂”化学快报。
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    0
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SONODA Takaaki其他文献

SONODA Takaaki的其他文献

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{{ truncateString('SONODA Takaaki', 18)}}的其他基金

STUDY ON THE ACIDITY OF POLYFLUORINATED CARBON COMPOUNDS
多氟碳化合物酸性的研究
  • 批准号:
    19550045
  • 财政年份:
    2007
  • 资助金额:
    $ 1.41万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
DEVELOPMENT OF NEW CATALYSIS REACTIONS WITH METAL SALTS OF FLUORINATED WEAKLY COORDINATED ANIONS
含氟弱配位阴离子金属盐新催化反应的开发
  • 批准号:
    12640572
  • 财政年份:
    2000
  • 资助金额:
    $ 1.41万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Reorganization of the citizenship education in Russia under the period of shifting regime
政权更迭时期俄罗斯公民教育的重组
  • 批准号:
    11610274
  • 财政年份:
    1999
  • 资助金额:
    $ 1.41万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
The Study of Generating Stabilized Phenyl Cations by Using New Super-Leaving Groups
利用新型超离去基团生成稳定苯基阳离子的研究
  • 批准号:
    07640726
  • 财政年份:
    1995
  • 资助金额:
    $ 1.41万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
The Study on the Mechanism of Conjugative Stabilization of Phenyl Cations
苯基阳离子共轭稳定机理的研究
  • 批准号:
    05804032
  • 财政年份:
    1993
  • 资助金额:
    $ 1.41万
  • 项目类别:
    Grant-in-Aid for General Scientific Research (C)
A New Type of Nonbenzenoid Aromatic Carbocation : 1, 6-Methano[10]AnnulenylCation.
一种新型非苯环芳香族碳正离子:1, 6-甲醇[10]环烯基阳离子。
  • 批准号:
    02804041
  • 财政年份:
    1990
  • 资助金额:
    $ 1.41万
  • 项目类别:
    Grant-in-Aid for General Scientific Research (C)
NUCLEOPHILIC SUBSTITUTION REACTION OF ARYL TRIFLATES VIA ARYL CATIONS
芳基三氟甲磺酸酯通过芳基阳离子的亲核取代反应
  • 批准号:
    60550614
  • 财政年份:
    1985
  • 资助金额:
    $ 1.41万
  • 项目类别:
    Grant-in-Aid for General Scientific Research (C)

相似海外基金

Modeling and Control of the Crystallization Kinetics of Organic Electrolytes
有机电解质结晶动力学的建模和控制
  • 批准号:
    8818627
  • 财政年份:
    1989
  • 资助金额:
    $ 1.41万
  • 项目类别:
    Standard Grant
Modeling and Control of the Crystallization Kinetics of Organic Electrolytes
有机电解质结晶动力学的建模和控制
  • 批准号:
    8613745
  • 财政年份:
    1987
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    $ 1.41万
  • 项目类别:
    Standard Grant
STUDIES ON ORGANIC ELECTROLYTES FOR BATTERIES
电池用有机电解质的研究
  • 批准号:
    60490015
  • 财政年份:
    1985
  • 资助金额:
    $ 1.41万
  • 项目类别:
    Grant-in-Aid for General Scientific Research (B)
Advanced learning strategies for potential energy surfaces applied to organic electrolytes
应用于有机电解质的势能表面的高级学习策略
  • 批准号:
    497249646
  • 财政年份:
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    $ 1.41万
  • 项目类别:
    Priority Programmes
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