Synthesis of Novel Copolymer from Vinyl Monomer and Heterocumulene.

由乙烯基单体和杂积烯合成新型共聚物。

• 批准号: 11650914
• 负责人: INOUE Shohei
• 金额: $ 2.3万
• 依托单位: Science University of Tokyo
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 1999
• 资助国家: 日本
• 起止时间: 1999 至 2000
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-11650914/
• 关键词: Lanthanoid Alkoxide; Polymerization; Anionic Polymerization; Addition Polymerization; Heterocumulene; Vinyl monomer; Keten; Methacrylic Ester

Block copolymers with chains of different structures in a molecule are expected as new polymer materials, and the syntheses require the selection of appropriate initiators for the living polymerization of corresponding monomers. We have already found that metalloporphyrins are excellent initiators for the living polymerization of a wide variety of monomers. The purpose of the present research is to establish the method of synthesis of block copolymers containing methyl methacrylate as a component, in view of industrial importance of poly (methyl methacrylate). As the result, we succeeded in the syntheses of block copolymers from methyl methacrylate and other alkyl methacrylates, alkyl acrylates, and methacrylonitrile, using aluminium polphyrin as initiator. Among these block copolymers, the property of methyl methacrylate methacrylonitrile copolymer is of particular interest, in that it forms micelles in appropriate solvents. The cast film exhibits a microphase separated structure, indicating the possibility of this block copolymer for application to novel polymer materials.

具有不同结构链段的嵌段共聚物有望成为一种新的聚合物材料，而合成需要选择合适的引发剂来进行相应单体的活性聚合。我们已经发现，金属卟啉是各种单体活性聚合的极佳引发剂。鉴于聚甲基丙烯酸甲酯的工业重要性，本研究的目的是建立以甲基丙烯酸甲酯为组分的嵌段共聚物的合成方法。在此基础上，以铝多卟啉为引发剂，成功地合成了甲基丙烯酸甲酯与其他甲基丙烯酸酯、丙烯酸酯和甲基丙烯腈的嵌段共聚物。在这些嵌段共聚物中，甲基丙烯酸甲酯-甲基丙烯腈共聚物的性能尤其令人感兴趣，因为它在适当的溶剂中形成胶束。铸膜层呈现微相分离结构，表明这种嵌段共聚物有可能应用于新型聚合物材料。

项目成果

H.Sugimoto,S.Inoue: "Design of Amphiphilic Intitiating Systems.Metalloporphyrin as Nucleophilic Growing Species and Organometallic Compound as Electrophilic Monomer Activator"Adv.Polym.Sci.. 146. 39-119 (1999)

H.Sugimoto,S.Inoue：“两亲引发系统的设计。金属卟啉作为亲核生长物种和有机金属化合物作为亲电子单体活化剂”Adv.Polym.Sci.. 146. 39-119 (1999)

H.Sugimoto, S.Inoue: "Design of Amphiphilic Initiating Systems. Metalloporphyrin as Nucleophilic Growing Species and Organometallic Compound as Electrophilic Monomer Activator."Adv.Polym.Sci.. 146. 39-119 (1999)

H.Sugimoto、S.Inoue：“两亲引发系统的设计。金属卟啉作为亲核生长物质和有机金属化合物作为亲电单体活化剂。”Adv.Polym.Sci.. 146. 39-119 (1999)

H.Sagimoto,S.Inoue: "Design of Amphiphilic Initiating Systems.Metalloporphyrin as Nucleophilic Growing Species and Organometallic Compound as Electrophilic Monomer Activator."Adv.Polym.Sci.. 146. 39-119 (1999)

H.Sagimoto,S.Inoue：“两亲引发系统的设计。金属卟啉作为亲核生长物种和有机金属化合物作为亲电单体活化剂。”Adv.Polym.Sci.. 146. 39-119 (1999)

H.Sugimoto,S.Inoue: "Design of Amphiphilic Initiating Systems. Metalloporphyrin as Nucleophilic Growing Species and Organometallic Compound as Electrophilic Monomer Activator."Advances in Polymer Science. 146. 39-119 (1999)

H.Sugimoto、S.Inoue：“两亲引发系统的设计。金属卟啉作为亲核生长物质和有机金属化合物作为亲电单体活化剂。”高分子科学进展。

H.Sugimoto,M.Kanai,S.Inoue: "Lanthanoid Alkoxide as A Novel Initiator for Synthesis of A Polyester by the Polymerization of Ketene"Macromol.Chem.Phys.,. 199. 1651-1655 (1998)

H.Sugimoto、M.Kanai、S.Inoue：“镧系醇盐作为乙烯酮聚合合成聚酯的新型引发剂”Macromol.Chem.Phys.，。