Three-Dimensional Molecular Alignment by the Use of Selective Adsorption on Solids

利用固体上的选择性吸附进行三维分子排列

• 批准号: 14550008
• 负责人: KUBONO Atsushi
• 金额: $ 1.92万
• 依托单位: Shizuoka University (2004)Kyoto Institute of Technology (2002-2003)
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2002
• 资助国家: 日本
• 起止时间: 2002 至 2004
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-14550008/
• 关键词: Quartz Crystal Microbalance; Liquid Crystals; Crystal Growth; Molecular Orientation; Adsorption; Anisotropy; Substrate Temperature; Visco-elasticity; 強誘電性; 残留分極

Organic thin films with high performance require three-dimensional (3D) regulation of the position and the orientation of molecules in organic thin films. The 3D regulation appears to be feasible by combination of one-dimensional out-of-plane regulation and two-dimensional in-plane alignment. The out-of-plane regulation involves the molecular layer epitaxy method firstly demonstrated by the author, and the out-of-plane alignment can be controlled by the interfacial anisotropy induced by the external electric field, the substrate crystal structure and the rubbing of the substrate surface. The electric and optical properties of these films are investigated. The mechanism of the specific structure formation is discussed from the quartz crystal microbalance study on the basis of a novel theoretical model.

高性能的有机薄膜需要对有机薄膜中分子的位置和取向进行三维（3D）调控。通过结合一维面外调节和二维面内对准，三维调节似乎是可行的。离面调控涉及作者首次论证的分子层外延方法，离面取向可以通过外电场诱导的界面各向异性、衬底晶体结构和衬底表面摩擦来控制。研究了这些薄膜的电学和光学性质。基于一种新的理论模型，从石英晶体微天平研究的角度探讨了这种特殊结构的形成机理。

项目成果

A.Kubono, T.Sato, K.Takemoto, R.Akiyama, K.Tanaka: "Striped Pattern Formation in Polymer-Dispersed Liquid Crystal Films"Liq.Cryst.. 30. 1181-1187 (2003)

A.Kubono、T.Sato、K.Takemoto、R.Akiyama、K.Tanaka：“聚合物分散液晶薄膜中的条纹图案形成”Liq.Cryst.. 30. 1181-1187 (2003)

Viscoelastic Analysis in the Formation of Organic Thin Films

• DOI: 10.1080/15421400500366449
• 发表时间: 2006-03
• 期刊: Molecular Crystals and Liquid Crystals
• 影响因子: 0.7
• 作者: A. Kubono;R. Akiyama

K.Noda, K.Ishida, A.Kubono, T.Horiuchi, H.Yamada, K.Matsushige: "Remanent Polarization Observed for Evaporated Films of Vinylidene Fluoride Oligomer"J.Appl.Phys.. 93. 2866-2870 (2003)

K.Noda、K.Ishida、A.Kubono、T.Horiuchi、H.Yamada、K.Matsushige：“偏二氟乙烯低聚物蒸发膜观察到的剩余偏振”J.Appl.Phys.. 93. 2866-2870 (2003)

Thermodynamic Model of Molecular Orientation in Vapor-deposite Organic Thin Films

气相沉积有机薄膜中分子取向的热力学模型

• 期刊: J.Appl.Phys. (in press)
• 作者: A.Kubono.R.Akiyama

Remanent polarization of evaporated films of vinylidene fluoride oligomers

• DOI: 10.1063/1.1540231
• 发表时间: 2003-03
• 期刊: Journal of Applied Physics
• 影响因子: 3.2
• 作者: K. Noda;K. Ishida;A. Kubono;T. Horiuchi;H. Yamada;K. Matsushige