Reaction Chemistry of Transition Metal Clusters
Reaction Chemistry of Transition Metal Clusters
批准号:
18105002
负责人:
SUZUKI Hiroharu
金额:
$73.3万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (S)
财政年份:
2006
资助国家:
日本
项目状态:
已结题
起止时间:
2006 至 2010
中文摘要
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英文摘要
We have systematically studied on the reaction chemistry of the transition metal polyhydride clusters for these five years in the quest to develop new and effective organic transformations achieved by the synergetic effect of the adjacent metal centers. And we have successfully achieved main subjects such as 1) synthesis of homo- and heterometallic clusters with higher nuclearity, 2) modification of the electronic and steric environment of the reaction site, 3) elucidation of the mechanism of the cluster reaction, and 4) development of new reactions catalyzed by the cluster complexes.
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Hydrogenation of a Trinuclearμ3-Imido Complex of Ruthenium: Homolytic or Heterolytic H-H Bond Cleavage?
钌三核μ3-亚胺络合物的氢化:均解或杂解 H-H 键断裂?
DOI:
--
发表时间:
2007
期刊:
Inorg. Chem.
影响因子:
4.6
作者:
[Kameo, H.; Nakajima, Y.; Suzuki, H. Eur. J.]
通讯作者:
H. Eur. J.
6族遷移金属とルテニウムを含む異種金属クラスター上での炭化水素配位子への官能基導入(3J31)
将官能团引入含有第 6 族过渡金属和钌的异质金属簇上的烃配体 (3J31)
DOI:
--
发表时间:
2007
期刊:
影响因子:
--
作者:
[市川利明, 伊藤淳一, 鈴木寛治]
通讯作者:
鈴木寛治
C-H Activation of Arene Substrates Mediated by Coodinative Unsaturation of Group 4 Metallocene-Iridium ELHB Hydrides
4 族茂金属-铱 ELHB 氢化物的配位不饱和介导的芳烃底物的 C-H 活化
DOI:
--
发表时间:
2008
期刊:
影响因子:
--
作者:
[大石理貴, 塩谷泰介, 鈴木寛治]
通讯作者:
鈴木寛治
Ru_5M骨格を有する六核ポリヒドリドクラスターの合成と構造(3E8-08)
Ru_5M骨架六核聚氢化物团簇(3E8-08)的合成与结构
DOI:
--
发表时间:
2008
期刊:
影响因子:
--
作者:
[望月信介, 高尾俊郎, 鈴木寛治]
通讯作者:
鈴木寛治
DOI:
--
发表时间:
2010
期刊:
Angew.Chem.Int.Ed. 49
影响因子:
--
作者:
[A.Tahara, m.Kajigaya, M.Moriya, T.Takao, H.Suzuki]
通讯作者:
H.Suzuki
共 41 条
Study for development of differentiation induction from iPS cell to dental pulp stem cell
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批准号:21792058
-
项目类别:Grant-in-Aid for Young Scientists (B)
-
资助金额:$2.75万
-
财政年份:2009
-
负责人:SUZUKI Hiroharu
-
依托单位:
Precision Designing of Multinuclear Transition Metal Complexes
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批准号:18064007
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
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资助金额:$48.7万
-
财政年份:2006
-
负责人:SUZUKI Hiroharu
-
依托单位:
Reduction and Synthetic Application of Dinitrogen Mediated by Metal Polyhydrido Clusters
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批准号:15205009
-
项目类别:Grant-in-Aid for Scientific Research (A)
-
资助金额:$27.37万
-
财政年份:2003
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负责人:SUZUKI Hiroharu
-
依托单位:
Control of Electronic Envionment ofReadion Site ofTransition Metal Cluster Complexes
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批准号:14078210
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
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资助金额:$19.84万
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财政年份:2002
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负责人:SUZUKI Hiroharu
-
依托单位:
REACTION FIELD CREATED BY METAL COMPLEXES
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批准号:07305039
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$3.52万
-
财政年份:1995
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负责人:SUZUKI Hiroharu
-
依托单位:
海外基金