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Controlled Synthesis of Multinuclear Metal Clusters Bridged by Thiolate Ligands

Controlled Synthesis of Multinuclear Metal Clusters Bridged by Thiolate Ligands
硫醇盐配体桥接的多核金属簇的受控合成
批准号:
19550061
负责人:
MATSUMOTO Tsuyoshi
金额:
$2.83万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2007
资助国家:
日本
项目状态:
已结题
起止时间:
2007 至 2009

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中文摘要
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英文摘要
New deca- and dodeca-nuclear cyclic nickel (II) complexes bridged by thioether-thiolate hybrid ligands and tert-butanethiolate ligands have been synthesized, which represents a new addition to the family of large cyclic Ni thiolate cluster. The site-selective nickel-thiolate bonds of the decanuclear complex were cleaved by treatment with I_2 to form a pentanuclear complex assuming a semicircular core structure. We have also synthesized a 3:1 site-differentiated [4Fe-4S] clusters carrying a tridentate thiolate ligand and a carboxylate ligand.
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DOI: 10.1002/anie.200907074
发表时间: 2010-06
期刊: Angewandte Chemie
影响因子: --
作者: [Chi Zhang;Tsuyoshi Matsumoto;Marek Samoc;Marek Samoc;Simon Petrie;S. Meng;T. Corkery;R. Stranger;Jinfang Zhang;M. Humphrey;K. Tatsumi]
通讯作者: Chi Zhang;Tsuyoshi Matsumoto;Marek Samoc;Marek Samoc;Simon Petrie;S. Meng;T. Corkery;R. Stranger;Jinfang Zhang;M. Humphrey;K. Tatsumi
DOI: --
发表时间: 2010
期刊:
影响因子: --
作者: [D.Liu, T.Matsumoto, K.Tatsumi]
通讯作者: K.Tatsumi
Synthesis and Reactions of MFe3S4 Clusters (M = Mo, Cu, Ni) Having a Tridentate Ligand Composed of Indolethiolates
具有由吲哚硫醇组成的三齿配体的 MFe3S4 簇(M = Mo、Cu、Ni)的合成和反应
DOI: --
发表时间: 2009
期刊:
影响因子: --
作者: [鳥海幸四郎, 橋本将一, 金物浩史, 藤原冴佳, 小澤芳樹, 満身稔, 中井英隆, 宮野洋祐, 林宜仁, 磯辺清, 劉東・松本剛・巽和行]
通讯作者: 劉東・松本剛・巽和行
Dinuclear Nickel Complexes modeling Acetyl-CoA Synthase
双核镍配合物模拟乙酰辅酶A合酶
DOI: --
发表时间: 2007
期刊:
影响因子: --
作者: [Ozawa Yoshiki, Yoshida Shingo, Kitayama Nobuyuki, Mitsumi Minoru, Toriumi Koshiro, Tsuge Kiyoshi, Araki Hiromi, Sasaki Yoichi, T. Matsumoto]
通讯作者: T. Matsumoto
48
    The development properties of the tactical knowledge and the transfer of the tactical skill in flag football
    • 批准号:
      24500692
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $2.75万
    • 财政年份:
      2012
    • 负责人:
      MATSUMOTO Tsuyoshi
    • 依托单位:
    Model Studies of Nickel Enzymes Included in Carbon Fixation Processes in Nature
    • 批准号:
      22550059
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $3.0万
    • 财政年份:
      2010
    • 负责人:
      MATSUMOTO Tsuyoshi
    • 依托单位:
    Catalysis of Active Site Models of Metalloenzymes Containing Dinuclear Metal Chalcogenide
    • 批准号:
      18065013
    • 项目类别:
      Grant-in-Aid for Scientific Research on Priority Areas
    • 资助金额:
      $20.48万
    • 财政年份:
      2006
    • 负责人:
      MATSUMOTO Tsuyoshi
    • 依托单位:
    海外基金