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Controlled Synthesis of Multinuclear Metal Clusters Bridged by Thiolate Ligands

Controlled Synthesis of Multinuclear Metal Clusters Bridged by Thiolate Ligands
硫醇盐配体桥接的多核金属簇的受控合成
批准号:
19550061
负责人:
MATSUMOTO Tsuyoshi
金额:
$2.83万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2007
资助国家:
日本
项目状态:
已结题
起止时间:
2007 至 2009

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中文摘要
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英文摘要
New deca- and dodeca-nuclear cyclic nickel (II) complexes bridged by thioether-thiolate hybrid ligands and tert-butanethiolate ligands have been synthesized, which represents a new addition to the family of large cyclic Ni thiolate cluster. The site-selective nickel-thiolate bonds of the decanuclear complex were cleaved by treatment with I_2 to form a pentanuclear complex assuming a semicircular core structure. We have also synthesized a 3:1 site-differentiated [4Fe-4S] clusters carrying a tridentate thiolate ligand and a carboxylate ligand.
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DOI: 10.1002/anie.200907074
发表时间: 2010-06
期刊: Angewandte Chemie
影响因子: --
作者: [Chi Zhang;Tsuyoshi Matsumoto;Marek Samoc;Marek Samoc;Simon Petrie;S. Meng;T. Corkery;R. Stranger;Jinfang Zhang;M. Humphrey;K. Tatsumi]
通讯作者: Chi Zhang;Tsuyoshi Matsumoto;Marek Samoc;Marek Samoc;Simon Petrie;S. Meng;T. Corkery;R. Stranger;Jinfang Zhang;M. Humphrey;K. Tatsumi
Host plant genome overcomes the lack of bacterial gene for symbiotic nitrogen fixation
宿主植物基因组克服了共生固氮细菌基因的缺乏
DOI: --
发表时间: 2009
期刊: Nature 462
影响因子: --
作者: [Hakoyama, T. ; Niimi, K. ; Watanabe, H. ; Tabata, R. ; Matsubara, J. ; Sato, S. ; Nakamura, Y. ; Tabata, S. ; Li, J. ; Matsumoto, T. ; Tatsumi, K. ; Nomura, M. ; Tajima, S. ; Ishizaka, M; Yano, K. ; Imaizumi-Anraku, H. ; Kawaguchi, M. ; Kouchi, H. ; Sugan]
通讯作者: H. ; Sugan
Acetyl CoA Synthase, a Key Player of Carbon Fixation in Nature
乙酰辅酶A合酶,自然界碳固定的关键角色
DOI: --
发表时间: 2009
期刊: Bull. Jpn. Soc. Coord. Chem. 54(Review)
影响因子: --
作者: [Matsumoto, T.]
通讯作者: T.
Evidence for a Rapid Degenerate Hetero-Cope-type Rearrangement in Cp*W(S)2-CH2-CH2-CH=CH2
Cp*W(S)2-CH2-CH2-CH=CH2 中快速简并异质-Cope 型重排的证据
DOI: --
发表时间: 2009
期刊: Chem. Asian J. 4
影响因子: --
作者: [Eweiner, F. ; Senda, S. ; Bergander, K. ; Muck-Lichtenfeld, C. ; Grimme, S. ; Frohlich, R. ; Aoyama, M. ; Kawaguchi, H. ; Ohki, Y. ; Matsumoto, T. ; Kehr, G. ; Tatsumi, K. ; Erker, G.]
通讯作者: G.
48
    The development properties of the tactical knowledge and the transfer of the tactical skill in flag football
    • 批准号:
      24500692
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $2.75万
    • 财政年份:
      2012
    • 负责人:
      MATSUMOTO Tsuyoshi
    • 依托单位:
    Model Studies of Nickel Enzymes Included in Carbon Fixation Processes in Nature
    • 批准号:
      22550059
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $3.0万
    • 财政年份:
      2010
    • 负责人:
      MATSUMOTO Tsuyoshi
    • 依托单位:
    Catalysis of Active Site Models of Metalloenzymes Containing Dinuclear Metal Chalcogenide
    • 批准号:
      18065013
    • 项目类别:
      Grant-in-Aid for Scientific Research on Priority Areas
    • 资助金额:
      $20.48万
    • 财政年份:
      2006
    • 负责人:
      MATSUMOTO Tsuyoshi
    • 依托单位:
    海外基金