Controlled Synthesis of Multinuclear Metal Clusters Bridged by Thiolate Ligands
Controlled Synthesis of Multinuclear Metal Clusters Bridged by Thiolate Ligands
批准号:
19550061
负责人:
MATSUMOTO Tsuyoshi
金额:
$2.83万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2007
资助国家:
日本
项目状态:
已结题
起止时间:
2007 至 2009
中文摘要
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英文摘要
New deca- and dodeca-nuclear cyclic nickel (II) complexes bridged by thioether-thiolate hybrid ligands and tert-butanethiolate ligands have been synthesized, which represents a new addition to the family of large cyclic Ni thiolate cluster. The site-selective nickel-thiolate bonds of the decanuclear complex were cleaved by treatment with I_2 to form a pentanuclear complex assuming a semicircular core structure. We have also synthesized a 3:1 site-differentiated [4Fe-4S] clusters carrying a tridentate thiolate ligand and a carboxylate ligand.
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DOI:
10.1002/anie.200907074
发表时间:
2010-06
期刊:
Angewandte Chemie
影响因子:
--
作者:
[Chi Zhang;Tsuyoshi Matsumoto;Marek Samoc;Marek Samoc;Simon Petrie;S. Meng;T. Corkery;R. Stranger;Jinfang Zhang;M. Humphrey;K. Tatsumi]
通讯作者:
Chi Zhang;Tsuyoshi Matsumoto;Marek Samoc;Marek Samoc;Simon Petrie;S. Meng;T. Corkery;R. Stranger;Jinfang Zhang;M. Humphrey;K. Tatsumi
Ligand Substitution Reactions of the Chloride-coordinated[3 : 1]Site-Differentiated[4Fe-4S]Clusters
氯配位[3:1]位点差异[4Fe-4S]簇的配体取代反应
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[D.Liu, T.Matsumoto, K.Tatsumi]
通讯作者:
K.Tatsumi
Synthesis and Reactions of MFe3S4 Clusters (M = Mo, Cu, Ni) Having a Tridentate Ligand Composed of Indolethiolates
具有由吲哚硫醇组成的三齿配体的 MFe3S4 簇(M = Mo、Cu、Ni)的合成和反应
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
[鳥海幸四郎, 橋本将一, 金物浩史, 藤原冴佳, 小澤芳樹, 満身稔, 中井英隆, 宮野洋祐, 林宜仁, 磯辺清, 劉東・松本剛・巽和行]
通讯作者:
劉東・松本剛・巽和行
Dinuclear Nickel Complexes modeling Acetyl-CoA Synthase
双核镍配合物模拟乙酰辅酶A合酶
DOI:
--
发表时间:
2007
期刊:
影响因子:
--
作者:
[Ozawa Yoshiki, Yoshida Shingo, Kitayama Nobuyuki, Mitsumi Minoru, Toriumi Koshiro, Tsuge Kiyoshi, Araki Hiromi, Sasaki Yoichi, T. Matsumoto]
通讯作者:
T. Matsumoto
Host plant genome overcomes the lack of bacterial gene for symbiotic nitrogen fixation
宿主植物基因组克服了共生固氮细菌基因的缺乏
DOI:
--
发表时间:
2009
期刊:
Nature 462
影响因子:
--
作者:
[Hakoyama, T. ; Niimi, K. ; Watanabe, H. ; Tabata, R. ; Matsubara, J. ; Sato, S. ; Nakamura, Y. ; Tabata, S. ; Li, J. ; Matsumoto, T. ; Tatsumi, K. ; Nomura, M. ; Tajima, S. ; Ishizaka, M; Yano, K. ; Imaizumi-Anraku, H. ; Kawaguchi, M. ; Kouchi, H. ; Sugan]
通讯作者:
H. ; Sugan
共 48 条
The development properties of the tactical knowledge and the transfer of the tactical skill in flag football
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批准号:24500692
-
项目类别:Grant-in-Aid for Scientific Research (C)
-
资助金额:$2.75万
-
财政年份:2012
-
负责人:MATSUMOTO Tsuyoshi
-
依托单位:
Model Studies of Nickel Enzymes Included in Carbon Fixation Processes in Nature
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批准号:22550059
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$3.0万
-
财政年份:2010
-
负责人:MATSUMOTO Tsuyoshi
-
依托单位:
Catalysis of Active Site Models of Metalloenzymes Containing Dinuclear Metal Chalcogenide
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批准号:18065013
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
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资助金额:$20.48万
-
财政年份:2006
-
负责人:MATSUMOTO Tsuyoshi
-
依托单位:
海外基金