Chemistry of Newπ-Electron Systems with Unusual Properties

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A series of newπ-electron materials with superb photophysical and electronic properties, such as intense solid-state emission, white emission, and high carrier mobility, have been developed based on new molecular designs exploiting characteristic features of main group elements, development of new reactions, and controlling of molecular alignments in the solid state. Some new design principles, such as the stabilization of organoboron materials and the construction of highly antiaromatic building units, have also been established.