Exploration of Purely Organic Mole cular Metal Based on Hydrogen-Bond and Charge-Transfer Interaction

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In order to explore purely organic molecular metals exhibiting peculiar properties and multiple functions based on the cooperation of hydrogen-bond and charge-transfer interactions, we have designed and synthesized new electron-donor molecules composed of tetrathiafulvalene analogues and hydrogen-bonding groups such as imidazole and nucleobases. These new molecules formed diverse network structures by robust hydrogen-bonds, and achieved highly conducting charge-transfer complexes with organic electron-acceptors molecules.