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Exploration of Molecular Materials based on Cooperative Proton-Electron Systems

基于协同质子电子系统的分子材料探索

基本信息

批准号：
06403008
负责人：
NAKASUJI Kazuhiro
金额：
$ 17.41万
依托单位：
Osaka University
依托单位国家：
日本
项目类别：
Grant-in-Aid for Scientific Research (A)
财政年份：
1994
资助国家：
日本
起止时间：
1994 至 1996
项目状态：
已结题

项目摘要

Search for new molecular materials based on the cooperative interactions between proton and electron has been performed. We developed a general strategy to explore new molecular materials. Cooperative proton-electron transfer (PET) in the hydrogen-bonded charge transfer (HBCT) systems might produce a molecular assembly of H-bonded neutral redicals. The solid state properties of such PET systems depend on the type and strength of the proton-electron cooperativity. A molecular level consideration leads to two reasonable molecular design strategies : the exploration of new electronic systems having smaller intermolecular CT gap and an electronic modification to stabilize H-bonded neutral radical state. According to the strategies, we synthesized new PET systems : (1) the donor and acceptor substituted quinhydrones, (2) the extended conjugated quinhydrones, and (3) the transition metal complexes having H-bonding networks. For example, as for the approach (1), we modified the prototype benzoquinhydrone by introducing the electron donor and the acceptor substituents. As for (2), we synthesized naphtho-, bipheno-, and stilben-quinhydrone as extended conjugated quinhydrones. In these quinhydrones, we have found cooperative phenomena between H-bonding and CT interaction. In order to expand the PET systems, new approach (3) are now actively performed. In the H-bonded transition metal complexes, we can utilize the additional characteristics of redox properties of the metal atoms and the intermolecular interactions between the metal atoms or between the metal atom and the ligand. As a first step, we succeeded to construct a H-bonded dimer model of the biimidazole transition metal complex. We are now concentrated to construct new H-bonded molecular systems of biimidazole-type and pteridine-type transition metal complexs.

基于质子和电子之间的协同作用，寻找新的分子材料。我们制定了一个探索新分子材料的总体策略。氢键电荷转移（HBCT）体系中的质子-电子协同转移（PET）可能产生氢键中性自由基的分子组装。这种PET系统的固态性质取决于质子-电子协同性的类型和强度。分子水平的考虑导致两个合理的分子设计策略：探索新的电子系统具有更小的分子间CT间隙和电子修饰，以稳定H-键合的中性自由基状态。根据这些策略，我们合成了新的PET体系：（1）给体和受体取代的醌氢酮，（2）扩展的共轭醌氢酮，（3）具有氢键网络的过渡金属配合物。例如，对于方法（1），我们通过引入电子给体和受体取代基来修改原型苯醌。对于（2），我们合成了萘并、联苯并和芪醌氢醌作为扩展的共轭醌氢酮。在这些化合物中，我们发现了氢键和CT相互作用之间的协同现象。为了扩展PET系统，现在积极执行新方法（3）。在氢键过渡金属配合物中，我们可以利用金属原子的氧化还原性质以及金属原子之间或金属原子与配体之间的分子间相互作用的额外特性。作为第一步，我们成功地构建了双咪唑过渡金属配合物的氢键二聚体模型。本论文的主要工作是构建新型的双咪唑型和蝶啶型过渡金属配合物的氢键分子体系。