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Optical properties of Frenkel exciton in crystalline thin films of π-conjugated polymers

Optical properties of Frenkel exciton in crystalline thin films of π-conjugated polymers
π共轭聚合物晶体薄膜中弗兰克尔激子的光学性质
批准号:
21740233
负责人:
KOBAYASHI Takashi
金额:
$2.83万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (B)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2010

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中文摘要
翻译
本文研究了π共轭聚合物结晶薄膜的激发态结构,着重讨论了链间相互作用的影响。虽然没有直接的证据表明,在晶体薄膜中的链间相互作用与相对较大的链间距离,它被发现,偶极禁止的状态,以及偶极允许的是同样的红移在晶体薄膜与较短的链间距离。在这项工作中,链间相互作用的性质进行了调查,其起源也进行了讨论。
英文摘要
The excited-state structure of crystalline thin films of π conjugated polymers has been studied, with a focus on the effect of interchain interaction. While there was no direct evidence indicating interchain interaction in crystalline thin films with relatively large interchain distances, it was found that the dipole forbidden states as well as dipole allowed ones are equally redshifted in crystalline thin films with a shorter interchain distance. In this work, the nature of the interchain interaction is investigated and its origin is also discussed.
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