Optical properties of Frenkel exciton in crystalline thin films of π-conjugated polymers
Optical properties of Frenkel exciton in crystalline thin films of π-conjugated polymers
批准号:
21740233
负责人:
KOBAYASHI Takashi
金额:
$2.83万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (B)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2010
中文摘要
本文研究了π共轭聚合物晶体薄膜的激发态结构,重点研究了链间相互作用的影响。虽然没有直接证据表明在较大的链间距离的晶体薄膜中存在相互作用,但发现在较短的链间距离的晶体薄膜中,偶极禁止态和偶极允许态同样红移。在这项工作中,研究了链间相互作用的性质,并讨论了其起源。
英文摘要
The excited-state structure of crystalline thin films of π conjugated polymers has been studied, with a focus on the effect of interchain interaction. While there was no direct evidence indicating interchain interaction in crystalline thin films with relatively large interchain distances, it was found that the dipole forbidden states as well as dipole allowed ones are equally redshifted in crystalline thin films with a shorter interchain distance. In this work, the nature of the interchain interaction is investigated and its origin is also discussed.
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