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Regioselective Arrangement and Bond Activation of the Metallacycles Composed of the Heavier Group 14 Elements

Regioselective Arrangement and Bond Activation of the Metallacycles Composed of the Heavier Group 14 Elements
重14族金属环的区域选择性排列和键活化
批准号:
21750057
负责人:
TANABE Makoto
金额:
$2.91万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (B)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2010

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项目成果

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中文摘要
翻译
本研究展示了硅、锗、锡金属环的新制备及其化学性质。利用这些胚金环前体,开发了一种新的、简便的合成低聚曼酮的方法。镍催化氢硅烷的脱氢偶联精确聚合制备了分子量分布较窄的环状低聚硅烷。
英文摘要
This study demonstrates new preparation of metallacycles composed of silicon, germanium, and tin and their chemical properties. A new and convenient synthetic method for oligogermanes was developed via these germametallacycles precursors. Nickel-catalyzed dehydrocoupling precise polymerizations of hydrosilanes produced cyclic oligosilanes with narrow molecular weight distribution.
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会议论文
Planar Tetranuclear and Dumbbell-shaped Octanuclear Pd Complexes with Bridging Silylene Ligands
具有桥连硅烯配体的平面四核和哑铃形八核 Pd 配合物
DOI: --
发表时间: 2009
期刊: Angew. Chem. Int. Ed 48
影响因子: --
作者: [山田哲行, 馬渡あかね, 田邊真, 小坂田耕太郎, 棚瀬知明]
通讯作者: 棚瀬知明
Development and practice of educational methods for engineering English using a CALL system with text chunking
  • 批准号:
    16K01156
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
  • 资助金额:
    $2.83万
  • 财政年份:
    2016
  • 负责人:
    TANABE Makoto
  • 依托单位:
Precise synthesis of cyclic polysilanes and the relative productsvia nickel and palladium key intermediates
  • 批准号:
    23750059
  • 项目类别:
    Grant-in-Aid for Young Scientists (B)
  • 资助金额:
    $3.0万
  • 财政年份:
    2011
  • 负责人:
    TANABE Makoto
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Development of the numerical method to solve dynamic interaction between a train and the railway structure after derailment during an earthquake
  • 批准号:
    20560230
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
  • 资助金额:
    $2.58万
  • 财政年份:
    2008
  • 负责人:
    TANABE Makoto
  • 依托单位:
Preparation of Multinuclear Complexes Containing the Linear Triplatinum Core with P-Ligands as New Metallaligands
  • 批准号:
    19750043
  • 项目类别:
    Grant-in-Aid for Young Scientists (B)
  • 资助金额:
    $2.36万
  • 财政年份:
    2007
  • 负责人:
    TANABE Makoto
  • 依托单位:
海外基金