Dielectric relaxation analyses of thin films of polyelectrolyte-surfactant complexes
Dielectric relaxation analyses of thin films of polyelectrolyte-surfactant complexes
批准号:
21750131
负责人:
NAKAMURA Kenji
金额:
$2.91万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (B)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2010
中文摘要
聚电解质-表面活性剂复合物具有有序的层状微结构,由于离子对、聚合物链段和侧链表面活性剂的运动,复合物表现出三种介电弛豫模式。表面活性剂从复合物的解离度估计为约。0.40。表面活性剂通过离子对运动的重复和聚合物链中多个电解质单体单元(约0.6nm)之间的解离过程来传输。
英文摘要
Polyelectrolyte-surfactant complexes with ordered lamellar micro-structure showed three dielectric relaxation modes due to the motions of ion-pairs, polymer segments, and side-chain surfactants. Degree of dissociation of surfactants from complexes was estimated to be ca.0.40. Surfactants are transported through the repetition of the ion-pair motion and dissociation process between plural electrolyte monomer units (ca 0.6nm) in a polymer chain.
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DOI:
--
发表时间:
2009
期刊:
影响因子:
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作者:
[水野誠, 津田旭彦, 中村健二, 小西隆士, 深尾浩次]
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2010
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[S. Takashima, H. Abe, M. Inouye, 中村健二]
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DOI:
--
发表时间:
2010
期刊:
The European Physical Journal Special Topics 189
影响因子:
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作者:
[Fukao, K., Oda, Y., Nakamura, K., Tahara, D.]
通讯作者:
D.
DOI:
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发表时间:
2010
期刊:
影响因子:
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[K. Nakamura, K. Fukao]
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K. Fukao
高分子積層薄膜のガラス転移とダイナミクス
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发表时间:
2010
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[鳥海優人, 大野かおる, 高遠徳尚, 加納将行・宮崎真一・伊藤耕介・平原和朗, 深尾浩次]
通讯作者:
深尾浩次
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