Molecular Design for Monomolecular Integration of Single Electron/Hole Tunneling Devices

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）：In this project we have developed a step-wise synthetic protocol for mono-molecular integration of single-charge (electron/hole) tunneling (SCT) devices. The SCT devices comprise four basic functional parts: Coulomb island, tunnel junction, capacitive junction, and wire. First, we have designed and synthesized various types of molecular building blocks as a candidate for these fundamental parts. Then, we have demonstrated the fabrication of trial models of single-charge "transistor", "turn-style", and "pump" from the molecular component libraries.