Synthesis of Multimetallic Complexes Having a Proximal Lewis Acidic Moiety and Application to Catalytic Transformations

本项目旨在合成具有近端刘易斯酸部分的多金属配合物，并开发新型多金属催化剂，这是其他单金属催化剂所没有的。在本项目中，我们成功地合成了带有新型[ PONNO]配体或[ PONNOP]配体的早/晚双金属配合物，并将其应用于催化转化。在某些反应中，多种金属的协同效应被观察到，以提高催化活性和产物选择性。

This project aimed at the synthesis of multimetallic complexes having a proximal Lewis acidic moiety and the development of novel multimetallic catalysis, which has not been achieved by other single metal catalysis. In this project, we successfully synthesized early/late bimetallic complexes bearing a novel[ PONNO] ligand or[ PONNOP] ligand, and applied to catalytic transformations. In some reactions, synergetic effects of multiple metals were observed to enhance the catalytic activity and product selectivity.