A Novel Approach to Solid State Dye Sensitized Solar Cells

固态染料敏化太阳能电池的新方法

• 批准号: 5399487
• 负责人: Professor Dr. Lukas Schmidt-Mende, Ph.D.
• 金额: --
• 依托单位: Arbeitsgruppe Hybrid Nanostructures
• 依托单位国家: 德国
• 项目类别: Emmy Noether International Fellowships
• 财政年份: 2003
• 资助国家: 德国
• 起止时间: 2002-12-31 至 2005-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/5399487?language=en
• 关键词: Novel; Approach; Solid; State; Dye

Solar energy is the world's biggest renewable energy source. However, the production of conventional solar cells is still very expensive and energy consuming. Organic solar cells are a new alternative and have the potential to be an environmentally friendly and cheap energy source. The conjugated materials combine the electronic properties of semiconductors and the solution processibility of polymeric materials. This proposal describes research on solid state dye sensitized solar cells, focussing on the replacement of liquid electrolytes with discotic liquid crystalline materials as efficient hole conductors. The self-organization of the discotics in the TiO2 matrix will be investigated. A systematic study of the correlation between the alignment of the discotics in this matrix and the performance of the solar cell will be performed. Characterisation of the cells and the charge recombination dynamics of the heterojunctions is central to the understanding of the underlying fundamental physical processes. It is directly relevant to all research in the field of high efficiency dye sensitized solar cells. This is a highly interdisciplinary project bridging concepts from the field of semiconductors, molecular electronics, macromolecular organic photophysics of complex electron donor acceptor systems, and physical chemistry of organic thin films.

太阳能是世界上最大的可再生能源。然而，传统太阳能电池的生产仍然非常昂贵和耗能。有机太阳能电池是一种新的替代能源，有可能成为一种环境友好和廉价的能源。共轭材料联合收割机结合了半导体的电子性质和聚合物材料的溶液加工性。该提案描述了固态染料敏化太阳能电池的研究，重点是用分散的液晶材料代替液体电解质作为有效的空穴导体。将研究二氧化钛基质中的自组织。系统地研究了该矩阵中的药物的排列与太阳能电池性能之间的相关性。表征的细胞和异质结的电荷复合动力学是核心的基本物理过程的理解。它与高效染料敏化太阳能电池领域的所有研究直接相关。这是一个高度跨学科的项目，将半导体、分子电子学、复杂电子给体受体系统的大分子有机电子物理学和有机薄膜的物理化学领域的概念联系起来。