Construction of a Nitrogenase Model Using Metal Cluster-Containing Metallothionein
Construction of a Nitrogenase Model Using Metal Cluster-Containing Metallothionein
批准号:
22655017
负责人:
HAYASHI Takashi
金额:
$2.25万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Challenging Exploratory Research
财政年份:
2010
资助国家:
日本
项目状态:
已结题
起止时间:
2010 至 2011
中文摘要
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英文摘要
The reduction of hydrazine derivatives by a synthetic metallothionein complex with iron ions was monitored. Particularly, the complex is found to bring about the reductive N-N bond cleavage of methyl red smoothly. In addition, the functional model of hydrogenase with iron-sulfur cluster was also prepared by the conjugation between apocytochrome c matrix and iron-carbonyl cluster. The obtained complex exhibits the hydrogenase activity toward the H2 generation in aqueous media.
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Modification and Functionalization of Hemoproteins
血红素蛋白的修饰和功能化
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[坂本昌巳, 他, Takashi Hayashi]
通讯作者:
Takashi Hayashi
A Hydrogenase Model Ssystem Based on the Sequence of Cytochrome c : Photochemical Hydrogen Evolution in Aqueous Media
基于细胞色素c序列的氢化酶模型系统:水介质中的光化学析氢
DOI:
--
发表时间:
2011
期刊:
Chem.Commun.
影响因子:
--
作者:
[Yohei Sano, et al]
通讯作者:
et al
A Hydrogenase Model Ssystem Based on the Sequence of Cytochrome c : Photochemical Hydrogen Evolution in Aqueous Media Chem
基于细胞色素c序列的氢化酶模型系统:水介质化学中的光化学析氢
DOI:
--
发表时间:
2011
期刊:
Commun
影响因子:
--
作者:
[Yohei Sano, Akira Onoda, and Takashi Hayashi]
通讯作者:
and Takashi Hayashi
鉄ヒドロゲナーゼシステムを指向した人工金属酵素の調製および分子間・分子内電子移動を利用した可視光駆動型水素発生反応
铁氢化酶系统人工金属酶的制备及可见光驱动的分子间和分子内电子转移制氢反应
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[佐野洋平, 小野田晃, 林高史]
通讯作者:
林高史
シトクロムcを用いた鉄ヒドロゲナーゼ活性中心モデルの構築
利用细胞色素c构建铁氢化酶活性中心模型
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[Y.Sano, A.Onoda, R.Sakurai, H.Kitagishi, T.Hayashi, 佐野洋平・小野田晃・林高史]
通讯作者:
佐野洋平・小野田晃・林高史
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国内基金
海外基金
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