Raman spectroscopic study on uranyl and neptunyl species in hydrate melts
Raman spectroscopic study on uranyl and neptunyl species in hydrate melts
批准号:
23760827
负责人:
FUJII Toshiyuki
金额:
$2.58万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (B)
财政年份:
2011
资助国家:
日本
项目状态:
已结题
起止时间:
2011 至 2013
中文摘要
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英文摘要
Intramolecular vibrational frequency of uranyl and neptunyl species in hydrate chloride melts was studied by Raman spectrometry and ab initio calculations. The Raman frequency experimentally obtained decreased with the increase of concentration of Cl in solvent chlorides. This is attributable to that hydration water molecules at the equatorial plane of actinyl are substituted by chloride ions. This was consistent with the calculation results.
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Raman Spectroscopic Study on Uranyl and Neptunyl Complexes in Concentrated Chloride Solutions
浓氯化物溶液中铀酰和庚烯配合物的拉曼光谱研究
DOI:
--
发表时间:
2013
期刊:
影响因子:
--
作者:
[Toshiyuki FUJII, Akihiro UEHARA, Yoshihiro KITATSUJI, and Hajimu YAMANA]
通讯作者:
and Hajimu YAMANA
Raman Spectroscopic Study on Uranyl and Neptunyl Complexes in Highly Concentrated Calcium Chloride
高浓度氯化钙中铀酰和庚烯配合物的拉曼光谱研究
DOI:
--
发表时间:
2013
期刊:
影响因子:
--
作者:
[Toshiyuki FUJII, Akihiro UEHARA, Yoshihiro KITATSUJI, and Hajimu YAMANA]
通讯作者:
and Hajimu YAMANA
Improvement of fatigue resistance in high conductivity copper alloysby microstructural control
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批准号:22560690
-
项目类别:Grant-in-Aid for Scientific Research (C)
-
资助金额:$2.91万
-
财政年份:2010
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负责人:FUJII Toshiyuki
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依托单位:
Spectroscopic study of neptunium complexation in hydrate melts
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批准号:20760594
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项目类别:Grant-in-Aid for Young Scientists (B)
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资助金额:$2.66万
-
财政年份:2008
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负责人:FUJII Toshiyuki
-
依托单位:
Microstructural control of high -strengthened copper alloys for post-Corson alloy
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批准号:19560697
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$2.91万
-
财政年份:2007
-
负责人:FUJII Toshiyuki
-
依托单位:
High strength and high conductivity nanoparticle-precipitated copper ally : optimizaiton of thermomechanical processing
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批准号:15560601
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$1.86万
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财政年份:2003
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负责人:FUJII Toshiyuki
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依托单位:
海外基金