Production of the Device for Measuring the Pressure Dependent Magnetization and its Application

压力相关磁化强度测量装置的研制及其应用

• 批准号: 09650712
• 负责人: YOSHIDA Hajime
• 金额: $ 2.05万
• 依托单位: Tohoku University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 1997
• 资助国家: 日本
• 起止时间: 1997 至 1998
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-09650712/
• 关键词: 3d transition metals; magnetic moment; chemical pressure; clamp-type high pressure vessel; Ti alloys; spin flop depending on temperature; ac susceptibility; MnBi; マンガン金属間化合物; クランプ式加圧装置; 高圧力; 磁気秩序; マイクロ・ボンベ

The appearance of the magnetic moment in the 3d transition alloys and compounds is closely related to the distance between the magnetic atoms. Not only the direct compression but also the substitution of ions with different ionic radius can change the distance effectively. This chemical pressure is useful to produce the negative pressure for which it is hard to be realized by the physical compression means. The magnetic properties of Gd_<1-x>Y_xCo_2 in Laves phase have been investigated by examining the chemical pressure and direct compression effect. In the present studies, we notice a clamp-type microbomb as a high pressure apparatus and searched the good nonmagnetic materials for yielding the high pressure more than 1.5 GPa. The titanium alloys (Ti-6Al-4V) which have been applied to jet engines and rockets is lighter (density = 4 g/cc) and is stable at low temperatures, and its magnetic properties show a Pauli paramagnetism. The magnetic susceptibility at 4.2 K is 2.56x10^<-6> emu/g and the value of the magnetization at 10 kOe for the used high pressure vessel (-50 cc) is 5 emu/g. The mechanical features of the test pieces show higher properties than Be-Cu alloys. Pressure in the high pressure vessel below room temperature has been calibrated by measuring the resistivity of Manganin. The pressure effect of the critical temperature on spin-flop depending on the temperature was measured with ac susceptibility as its application. When Mn magnetic moments are along c-axis in the NiAs-type crystal structure, the volume of the sample becomes larger comparing with when magnetic ones are in c-plane and the value of the moment also becomes large.

三维过渡合金和化合物中磁矩的出现与磁性原子之间的距离密切相关。除了直接压缩外，不同离子半径离子的置换也能有效地改变距离。这种化学压力有助于产生用物理压缩手段难以实现的负压。通过化学压力和直接压缩效应研究了Gd_<1-x>Y_xCo_2在Laves相中的磁性能。在本研究中，我们注意到钳型微弹作为高压装置，并寻找了产生大于1.5 GPa高压的良好非磁性材料。应用于喷气发动机和火箭的钛合金（Ti-6Al-4V）较轻（密度= 4 g/cc），在低温下稳定，其磁性表现为泡利顺磁性。在4.2 K时磁化率为2.56 × 10^<-6> emu/g，使用的高压容器（-50 cc）在10 K时磁化强度为5 emu/g。试样的力学性能表现出比Be-Cu合金更高的性能。通过测量锰的电阻率，对常温下高压容器中的压力进行了标定。以交流磁化率为应用，测量了临界温度对自旋触发器的压力效应随温度的变化。在nias型晶体结构中，当Mn磁矩沿c轴时，样品的体积比磁矩沿c平面时大，磁矩值也变大。

项目成果

Hajime Yoshida: "Pressure Effect on the Curie Tempertaure of Intermetallic Compounds Gd_<1-x>Y_xCo_2" The Review of High Pressure Science and Technology. 7. 560-652 (1998)

Hajime Yoshida：“压力对金属间化合物Gd_<1-x>Y_xCo_2居里温度的影响”高压科学与技术评论。

Hajime YOSHIDA: "Pressure Effect on the Curie Temperalure of Intermetallic Campounds Gd_<1-x>Y_xCo_2" The Review of High Pressure Science and Technolagy. 7. 650-652 (1998)

Hajime YOSHIDA：“压力对金属间化合物Gd_<1-x>Y_xCo_2居里温度的影响”高压科学技术评论。

Hajime Yoshida: "Pressure Effect on the Curie Temperature of Intermetallic Compounds Gd_<1-X>Y_XCo_2" The Review of High Pressure Science and Technology. 7. 650-652 (1998)

Hajime Yoshida：“压力对金属间化合物Gd_<1-X>Y_XCo_2居里温度的影响”高压科学与技术评论。