Emergent organocopper complexes as robust catalysts for electrosynthesis

新兴有机铜配合物作为电合成的强大催化剂

• 批准号: DP240101902
• 负责人: Prof Paul Bernhardt
• 金额: $ 36.11万
• 依托单位: The University of Queensland
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2024
• 资助国家: 澳大利亚
• 起止时间: 2024-09-01 至 2027-08-30
• 项目状态: 未结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP240101902
• 关键词: Emergent; organocopper; complexes; robust; catalysts

The capture and stabilisation of highly reactive chemical species is critical to making advances in the synthesis of novel materials, agrochemicals and pharmaceuticals. Metal-bound carbanions are essential components of carbon-carbon bond forming reactions. This project aims to develop an unprecedented family of copper catalysts and deliver an innovative and versatile chemical reactivity platform. Expected outcomes of this project include methods of tempering and unleashing the high reactivity of these species by controlling the oxidation state of the copper ion. Benefits of these outcomes include fundamental understanding of the reactivity of a new class of copper complex that has potential commercial applications in catalysis.

高活性化学物种的捕获和稳定对于在新材料、农用化学品和药物的合成方面取得进展至关重要。金属结合的碳负离子是碳-碳键形成反应的重要组成部分。该项目旨在开发史无前例的铜催化剂系列，并提供一个创新和多功能的化学反应平台。该项目的预期结果包括通过控制铜离子的氧化状态来回火和释放这些物种的高反应性的方法。这些成果的好处包括从根本上了解一类在催化方面具有潜在商业应用的新型铜络合物的反应性。