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HETEROCYCLIC APPROACHES TO THE CYCLOPEPTIDE ALKALOIDS

HETEROCYCLIC APPROACHES TO THE CYCLOPEPTIDE ALKALOIDS
环肽生物碱的杂环方法
批准号：
3275379
负责人：
BRUCE H. LIPSHUTZ
金额：
$10.02万
依托单位：
UNIVERSITY OF CALIFORNIA SANTA BARBARA
依托单位国家：
美国
项目类别：
财政年份：
1980
资助国家：
美国
项目状态：
已结题
起止时间：
1980-08-01 至 1988-06-30
来源：
https://reporter.nih.gov/project-details/3275379
关键词：
alkaloids dipeptides drug design /synthesis /production heterocyclic compounds ionophores

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英文摘要
The proposed research deals with the incorporation of highly functionalized heterocycles into a cyclophane network which, via one or more mild and efficient chemical events, is unmasked to afford the skeleton characteristic of the cyclo-peptide alkaloids. Each is discussed, therefore, as potential intermediates which are to function as latent diamide/dipeptide equivalents in these schemes. Preliminary work has demonstrated the viability of such an approach in two acyclic systems. The natural products show considerable promise as ionophoric agents, in addition to other biological activities.
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