Catalytic Science in the Harwell Research Centre

哈韦尔研究中心的催化科学

• 批准号: EP/I019693/1
• 负责人: Richard Catlow
• 金额: $ 209.61万
• 依托单位: University College London
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2011
• 资助国家: 英国
• 起止时间: 2011 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FI019693%2F1
• 关键词: Catalytic; Science; Harwell; Research; Centre

Catalysis is a core area of science that lies at the heart of the chemicals industry - an immensely successful and important part of the overall UK economy, where in recent years the UK output has totalled over 50B and is ranked 7th in the world. This position is being maintained in the face of immense competition worldwide. For the UK to maintain its leading position it is essential that innovation in research is maintained, which can be achieved through bringing together the internationally leading academic activity that exists in the UK in this key area of contemporary science. We therefore, aim to create a Centre for Catalysis at the central facilities which will help to keep the UK at the forefront of this crucial scientific and technological sector. The Centre will be established in the Research Complex at Harwell which will allow us both to work closely with the central facilities, to whose development the project will also contribute, and to interact with and contribute to the broader scientific community on the Harwell/RAL Campus The major developments in the in situ characterisation of catalytic materials that have taken place in the recent years have been of immense importance in addressing the complex scientific problems posed by catalytic science The Centre will therefore in pursuing a wide ranging programme of research in catalytic science, develop state-of-the art in situ facilities that will be used for experiments to be conducted at the Diamond, Synchrotron Radiation, ISIS Neutron Scattering and Central Laser Facilities. Such experiments will allow us to probe the structure and evolution of catalysts at the molecular level during their operation; but their effectiveness will require the on-line studies to be integrated with off line experimentation in the Complex, within which we will establish a broad range of experimental facilities. An extensive programme of applications will be undertaken, with strong emphasis on the following central themes in contemporary catalytic science:* Sustainable Catalyst Technologies for Organic Transformations* Catalysis for alternative fuels* Catalysis in the Protection of the EnvironmentBy coordinating the expertise of the collaborative groups, in novel areas of catalytic science enabled by the facilities on the Harwell/RAL campus, we will provide a platform for new initiatives that will provide a hub for UK catalysis research and will give substantial added value to the existing investment in catalytic science. Moreover by working together, the UK scientific team will be able take centre stage and lead the world in this crucial field.The impact of the Centre will be further promoted by a vigorous and effective dissemination strategy which will develop strong interactions with a wide range of academic and industrial groups and with the broader scientific community.

催化是化学工业的核心科学领域，化学工业是英国整体经济中非常成功且重要的组成部分，近年来英国的产出总计超过 50B，位居世界第七位。面对全球激烈的竞争，这一地位得以保持。英国要保持领先地位，保持研究创新至关重要，这可以通过汇集英国在当代科学这一关键领域的国际领先学术活动来实现。因此，我们的目标是在中央设施中建立一个催化中心，这将有助于英国保持在这一关键科学技术领域的前沿。该中心将建在哈韦尔的研究综合体中，这将使我们能够与中央设施密切合作，该项目也将为其发展做出贡献，并与哈韦尔/RAL园区更广泛的科学界互动并为之做出贡献。 范围广泛的催化科学研究计划，开发最先进的现场设施，用于在钻石、同步辐射、ISIS 中子散射和中央激光设施进行实验。这些实验将使我们能够在分子水平上探究催化剂在运行过程中的结构和演变；但其有效性需要将在线研究与综合体中的离线实验相结合，我们将在其中建立广泛的实验设施。将开展广泛的应用计划，重点关注当代催化科学的以下中心主题：*有机转化的可持续催化剂技术*替代燃料的催化*环境保护中的催化通过协调合作小组的专业知识，在哈韦尔/劳尔校区设施支持的催化科学新领域，我们将为新举措提供一个平台，这些举措将提供 英国催化研究中心，将为催化科学的现有投资带来巨大的附加值。此外，通过共同努力，英国科学团队将能够在这一关键领域占据中心舞台并引领世界。该中心的影响力将通过积极有效的传播战略得到进一步提升，该战略将与广泛的学术和工业团体以及更广泛的科学界建立强有力的互动。

项目成果

Influence of Synthesis Conditions on the Structure of Nickel Nanoparticles and their Reactivity in Selective Asymmetric Hydrogenation

• DOI: 10.1002/cctc.201901955
• 发表时间: 2020-01
• 期刊: ChemCatChem
• 影响因子: 4.5
• 作者: Rosa Arrigo;Simone Gallarati;M. Schuster;Jake M Seymour;D. Gianolio;I. Silva;J. Callison;Hao Feng;J. Proctor;P. Ferrer;F. Venturini;D. Grinter;G. Held

Monitoring dynamics of defects and single Fe atoms in N-functionalized few-layer graphene by in situ temperature programmed scanning transmission electron microscopy

• DOI: 10.1016/j.jechem.2021.05.005
• 发表时间: 2021-06-01
• 期刊: JOURNAL OF ENERGY CHEMISTRY
• 影响因子: 13.1
• 作者: Arrigo, Rosa;Sasaki, Takeo;Schuster, Manfred Erwin
• 通讯作者: Schuster, Manfred Erwin

The adsorption and dissociation of CO on Fe(111)

CO在Fe(111)上的吸附和解离

• DOI: 10.1016/j.susc.2014.02.019
• 发表时间: 2014
• 期刊: Surface Science
• 影响因子: 1.9
• 作者: Booyens S

The electronic structure, surface properties, and in situ N2O decomposition of mechanochemically synthesised LaMnO3.

• DOI: 10.1039/d0cp00793e
• 发表时间: 2020-06
• 期刊: Physical chemistry chemical physics : PCCP
• 作者: Rachel H Blackmore;M. E. Rivas;George F Tierney;K. Mohammed;Donato Decarolis;S. Hayama;F. Venturini;G. Held;Rosa Arrigo;M. Amboage;Pip Hellier;Evan W. Lynch;M. Amri;M. Casavola;Tugce Eralp Erden;P. Collier;P. Wells

Dynamics at Polarized Carbon Dioxide-Iron Oxyhydroxide Interfaces Unveil the Origin of Multicarbon Product Formation

• DOI: 10.1021/acscatal.1c04296
• 发表时间: 2022-01-07
• 期刊: ACS CATALYSIS
• 影响因子: 12.9
• 作者: Arrigo, Rosa;Blume, Raoul;Centi, Gabriele
• 通讯作者: Centi, Gabriele