University of Glasgow - Equipment Account

格拉斯哥大学 - 设备帐户

• 批准号: EP/J014478/1
• 负责人: Muffy Calder
• 金额: $ 463.05万
• 依托单位: University of Glasgow
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2011
• 资助国家: 英国
• 起止时间: 2011 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FJ014478%2F1
• 关键词: University; Glasgow; Equipment; Account

The peculiar behaviour of liquid and supercooled water has been baffling science for at least 236 years and is still seen as a major challenge facing chemistry today (Whitesides & Deutch, Nature 469, 21 (2011)). In the 1970s and 1990s, it was suggested that such strange behaviour might be caused by thermodynamic transitions, possibly even a second critical point. This second critical point would terminate a coexistence line between low- and high-density amorphous phases of water. Unfortunately, this second critical point (if it exists) and the associated polyamorphic liquid-liquid transition is difficult to study as it is thought to lie below the homogeneous nucleation temperature in a region known as "no man's land" (Angell, Science 319, 582 (2008)). Recent work, notably by Hajime Tanaka of the University of Tokyo (see, for example, Nature Communications 1, 16 (2010)) has suggested that such a second critical point and the associated liquid-liquid transition might be much more common. In fact, liquid-liquid transitions have now been observed in a range of highly interacting atomic liquids such as phosphorus, gallium, silicon, germanium, and bismuth, and even in supercooled Y2O3-Al2O3. Theoretical considerations (independently by the groups of Hajime Tanaka and Eugene Stanley) suggest that liquid-liquid transitions should be very common even in molecular liquids. However, the only molecular liquid in which such a transition is now well established is triphenyl phosphite, which has been studied by Tanaka. Unfortunately, the effect is only observed when the liquid is deeply supercooled and extremely viscous. This precludes a detailed and definitive study of the phenomenon and has led to considerable controversy.In preliminary work, we have discovered the presence of a liquid-liquid transition in a few simple organic liquids above their melting point where the viscosity is low. This will allow a unique series of comprehensive studies of the liquid-liquid transition involving repeated thermal cycling through the transition. A number of experimental techniques will be used providing access to dynamics from femtosecond to kiloseconds and structure from molecular to macroscopic scales. Spectroscopic imaging techniques will be used to provide insight into molecular interactions and molecular-scale environments and their association with the liquid-liquid transition. This will allow detailed comparison with theoretical models and will give unprecedented insight into the physical origin of these phenomena and allow manipulation and control in future applications. To ensure maximum impact of the experimental work, it is critical to have strong ties with experts in the theory and simulation of LLTs and we have secured the collaboration of H. Eugene Stanley.

液体和过冷水的特殊行为已经困扰了科学界至少236年，并且仍然被视为今天化学面临的主要挑战（Whitesides & Deutch, Nature 469, 21(2011)）。在20世纪70年代和90年代，有人提出，这种奇怪的行为可能是由热力学转变引起的，甚至可能是第二个临界点。这第二个临界点将终止水的低相和高密度非晶态相之间的共存线。不幸的是，第二个临界点（如果存在的话）和相关的多晶液-液转变很难研究，因为它被认为位于一个被称为“无人区”的区域，低于均匀成核温度（Angell, Science 319, 582(2008)）。最近的研究，特别是东京大学的Hajime Tanaka的研究（例如，参见《自然通讯》第1期，第16期（2010））表明，这样的第二个临界点和相关的液-液过渡可能更为常见。事实上，在一系列高度相互作用的原子液体中，如磷、镓、硅、锗和铋，甚至在过冷的Y2O3-Al2O3中，已经观察到液-液转变。理论上的考虑（由Hajime Tanaka和Eugene Stanley小组独立提出）表明，即使在分子液体中，液-液过渡也应该是非常普遍的。然而，目前唯一确定了这种转变的分子液体是三苯基亚磷酸酯，田中已经对其进行了研究。不幸的是，这种效应只有在液体极度过冷和极度粘稠的情况下才能观察到。这就排除了对这一现象的详细和明确的研究，并导致了相当大的争议。在初步工作中，我们发现在一些粘度较低的简单有机液体的熔点以上存在液-液过渡。这将允许对液-液转变进行一系列独特的综合研究，包括通过转变进行重复的热循环。许多实验技术将用于提供从飞秒到千秒的动力学和从分子到宏观尺度的结构。光谱成像技术将用于洞察分子相互作用和分子尺度环境及其与液-液转变的关系。这将允许与理论模型进行详细的比较，并将对这些现象的物理起源提供前所未有的见解，并允许在未来的应用中进行操作和控制。为了确保实验工作的最大影响，与llt理论和模拟专家建立牢固的联系至关重要，我们已经获得了H. Eugene Stanley的合作。

项目成果

Frustration of crystallisation by a liquid-crystal phase.

• DOI: 10.1038/srep42439
• 发表时间: 2017-02-17
• 期刊: Scientific reports
• 影响因子: 4.6
• 作者: Syme CD;Mosses J;González-Jiménez M;Shebanova O;Walton F;Wynne K
• 通讯作者: Wynne K

Crystal templating through liquid-liquid phase separation.

通过液-液相分离进行晶体模板化。

• DOI: 10.1039/c4cc07880b
• 发表时间: 2015
• 期刊: Chemical communications (Cambridge, England)
• 作者: Mosses J

Influence of alkyne spacers on the performance of thiophene-based donors in bulk-heterojunction organic photovoltaic cells

• DOI: 10.1016/j.dyepig.2021.109152
• 发表时间: 2021-01
• 期刊: Dyes and Pigments
• 影响因子: 4.5
• 作者: John Marques dos Santos;Marios Neophytou;A. Wiles;Calvyn T Howells;R. S. Ashraf;I. McCulloch;G. Cooke