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New microporous polymers for carbon dioxide selective membranes

用于二氧化碳选择性膜的新型微孔聚合物

基本信息

批准号：
EP/K008102/2
负责人：
Neil McKeown
金额：
$ 36.71万
依托单位：
University of Edinburgh
依托单位国家：
英国
项目类别：
Research Grant
财政年份：
2014
资助国家：
英国
起止时间：
2014 至无数据
项目状态：
已结题

来源：
https://gtr.ukri.org/projects?ref=EP%2FK008102%2F2
关键词：
New microporous polymers carbon dioxide

项目摘要

Energy security and climate change are pressing global concerns. In this context, high performance carbon dioxide selective gas separation membranes are required for purification of biogas, natural gas and efficient carbon capture technology. Carbon dioxide removal using a polymer membrane system offers advantages over alternative processes, most notably energy efficiency, as membranes do not require thermal regeneration, a phase change or active moving parts in their operation. For any gas separation membrane, it is desirable to have good selectivity for the desired gas component combined with high permeability (i.e. flux), to minimise the required size of the system. Unfortunately, current highly permeable polymers possess insufficient selectivity and conversely highly selective polymers possess low permeability. Therefore, the goal of enhancing the selectivity of highly permeable polymers, such as Polymers of Intrinsic Microporosity (PIMs), is an important challenge in chemical engineering. We propose an integrated, multi-skilled and multi-national programme of research that will combine molecular modelling, computational simulation of polymer packing, polymer synthesis, gas adsorption and gas permeability studies to develop polymers for use as highly carbon dioxide-selective membranes. PIMs will be prepared with the direct incorporation of benzimidazole and pyrrolone heterocyclic units into the polymer chains. Calculations show that these heterocyclic units possess a high affinity for carbon dioxide. The proposed polymer design conforms to the concept of PIMs, which requires polymers chains that are both rigid and contorted to frustrate space-efficient packing in the solid state. The combined use of molecular modelling and polymer packing simulations to understand gas permeability and, ultimately, predict performance of PIMs as membrane materials will enable the design of further optimised polymers. Achieving the objective of the proposed research programme would be an important first step towards providing carbon dioxide selective membranes of real utility in biogas and natural gas purification, carbon capture and for several niche applications.

能源安全和气候变化是紧迫的全球关切。在这种情况下，需要高性能的二氧化碳选择性气体分离膜来净化沼气、天然气和高效的碳捕获技术。使用聚合物膜系统去除二氧化碳比其他方法更有优势，最显著的是能源效率，因为膜在操作中不需要热再生、相变或活动部件。对于任何气体分离膜，希望对所需的气体组分具有良好的选择性，并结合高渗透性（即通量），以最小化所需的系统尺寸。不幸的是，目前的高渗透性聚合物的选择性不足，相反，高选择性聚合物具有低渗透性。因此，提高高渗透性聚合物（如固有微孔聚合物）的选择性是化学工程中的一个重要挑战。我们提出了一个综合的、多技术的和多国的研究项目，将结合分子建模、聚合物包装的计算模拟、聚合物合成、气体吸附和气体渗透性研究来开发用于高二氧化碳选择性膜的聚合物。将苯并咪唑和吡咯酮杂环单元直接掺入到聚合物链中制备pim。计算表明，这些杂环单位对二氧化碳具有很高的亲和力。所提出的聚合物设计符合PIMs的概念，该概念要求聚合物链既刚性又扭曲，以在固态中挫败空间效率高的包装。结合分子建模和聚合物填充模拟来了解气体渗透性，并最终预测pim作为膜材料的性能，这将有助于进一步优化聚合物的设计。实现拟议的研究方案的目标将是重要的第一步，以提供在沼气和天然气净化、碳捕获和若干利基应用方面真正有用的二氧化碳选择膜。