CONTROL OF DIELS ALDER REACTIONS BY SURFACTANT BASED ORGANIZED MEDIA

本项目的目的是利用胶束和囊泡 系统，基于功能化的表面活性剂， Diels-Alder反应的区域选择性。 的主要部分 该项目涉及新型离子的合成和表征， 含有1，3-二烯和亲二烯体组分的表面活性剂 Diels-Alder系统 表征通常包括低和 利用快原子轰击的高分辨率质谱分析 (FAB)电离 我们的许多表面活性剂不适合于 燃烧分析 因此，表面活性剂的高分辨率测量 离子提供了燃烧分析无法提供的成分证据。

The objective of this project is to use micellar and vesicular systems, based on functionalized surfactants, for control of the regioselectivity of Diels-Alder reactions. A major part of the project involves the synthesis and characterization of novel ionic surfactants containing the 1,3-diene and dienophile components of the Diels-Alder systems. Characterization often includes both low and high resolution mass spectral analysis utilizing fast atom bombardment (FAB) ionization. Many of our surfactants are not amenable to combustion analysis. Thus high resolution measurements of surfactant ions provides proof of composition that combustion analysis cannot.