Metallurgy at Extreme Conditions: Molten Iron-Alloy Constraints on the Light Elements in Earth's Core

极端条件下的冶金：熔融铁合金对地核轻元素的限制

• 批准号: NE/F019084/1
• 负责人: Michael Walter
• 金额: $ 33.35万
• 依托单位: University of Bristol
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2009
• 资助国家: 英国
• 起止时间: 2009 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=NE%2FF019084%2F1
• 关键词: Metallurgy; Extreme; Conditions; Molten; Iron

One of the outstanding mysteries in the Earth sciences is the composition of the core. We know from seismic and cosmochemical constraints that the core is made of a nearly pure iron (~95% Fe + 5% Ni), and that the inner core is solid and the outer core is molten. However, based on our knowledge of the behavior of molten iron at the extreme pressure and temperature conditions of the core, it is apparent that there must be some other light element or elements dissolved in the molten outer core as well. It is thought that the light element is related to convection in the outer core and is therefore important for spawning the Earth's magnetic field. The nature and abundance of the light element will also determine the kinds of reactions that might occur at the boundary between mantle silicate and the molten metal core. For the last half-century the primary candidates for the light elements in the core have included H, O, S, C, and Si. We will never be able to sample the core directly, hollywood movies notwithstanding, so other approaches are required to deduce the identity of the light elements. Basically, the approach has been to try and determine which elements can dissolve into molten iron at core conditions using experiment and theory. A perusal of the vast literature on this subject reveals that individual elements and cocktails of elements have come into, out of, and back into favor with time. Different experimental and theoretical approaches often lead to very different interpretations as to the identity of the light elements. Here we propose a method for deducing the light element in the core that relies on a combination of experiment, thermodynamic modeling, and seismic observations. Seismic data constrain the velocity at which compressional waves can move through molten iron as well as the density. They can also detect whether the core liquid has separated into more than one liquid (immiscibility). In principle, if one knows the same properties for various iron alloy - light element mixtures, one can deduce the composition of the core. The seismic observations are available. An internally consistent model for the properties of molten alloys at core conditions is not. However, thermodynamic relationships allow the physical properties to be determined through the equation of state of molten alloys. The parameters required to develop the thermodynamic model can be deduced through the melting curves of iron - light element alloy compositions. Here, we are proposing to make measurements of the melting curves of two-component (binary) alloys such as FeO, Fe3C, FeS, FeH and FeSi in order to derive the quantities required for the thermodynamic model. We have developed robust techniques in our lab for measuring melting points to very high pressures and temperatures using the laser-heated diamond anvil cell. Further, we have developed an exciting and novel new X-ray imaging technique with which we can measure directly the minimum melting compositions (eutectics) in iron - light element systems. These data further help constrain the thermodynamic models. In summary, we will use an experimental approach to measure how iron - light element alloys melt and from this data we will develop a multi-component thermodynamic model that will allow us to predict the seismic wave velocities and density of a wide range of possible core liquids. We will then compare the model with actual observations to deduce the identity of the elusive light elements in the molten outer core.

地核的构成是地球科学中最大的谜团之一。我们从地震和宇宙化学的限制知道，核心是由几乎纯铁（~95%铁+ 5%镍），内核是固体，外核是熔融的。然而，根据我们对熔融铁在核心极端压力和温度条件下的行为的了解，很明显，一定有一些其他轻元素也溶解在熔融的外核心中。轻元素被认为与外核的对流有关，因此对产生地球磁场很重要。轻元素的性质和丰度也将决定地幔硅酸盐和熔融金属核之间可能发生的反应类型。在过去的半个世纪里，核心轻元素的主要候选者包括H、O、S、C和Si。我们永远无法直接对地核进行取样，尽管好莱坞电影如此，因此需要其他方法来推断光元素的身份。基本上，这种方法一直是尝试和确定哪些元素可以溶解到熔融铁在核心条件下使用实验和理论。细读关于这个主题的大量文献可以发现，随着时间的推移，单个元素和元素的鸡尾酒已经进入，退出，并重新受到青睐。不同的实验和理论方法往往导致对轻元素身份的非常不同的解释。在这里，我们提出了一种方法来推断轻元素的核心，依赖于实验，热力学模型和地震观测的组合。地震数据限制了压缩波通过铁水的速度以及密度。它们还可以检测核心液体是否已分离成一种以上的液体（不可分离性）。原则上，如果人们知道各种铁合金-轻元素混合物的相同性质，就可以推断出核心的组成。地震观测是可用的。一个内部一致的模型熔融合金在核心条件下的属性是没有的。然而，热力学关系允许通过熔融合金的状态方程来确定物理性质。建立热力学模型所需的参数可以通过铁-轻元素合金成分的熔化曲线来推导。在这里，我们建议测量两组分（二元）合金，如FeO，Fe 3C，FeS，FeH和FeSi的熔化曲线，以获得热力学模型所需的量。我们在实验室中开发了强大的技术，用于使用激光加热金刚石砧座测量非常高的压力和温度的熔点。此外，我们已经开发了一种令人兴奋的和新颖的新的X射线成像技术，我们可以直接测量铁轻元素系统中的最小熔融成分（共晶）。这些数据进一步帮助约束热力学模型。总之，我们将使用一种实验方法来测量铁-轻元素合金如何熔化，并且从这些数据中，我们将开发一种多组分热力学模型，该模型将使我们能够预测各种可能的地核液体的地震波速度和密度。然后，我们将把模型与实际观测结果进行比较，以推断熔融外核中难以捉摸的轻元素的身份。

项目成果

Calibration of Raman spectroscopy in the stress measurement of air-plasma-sprayed yttria-stabilized zirconia.

空气等离子体喷涂氧化钇稳定氧化锆应力测量中拉曼光谱的校准。

• DOI: 10.1366/12-06676
• 发表时间: 2012
• 期刊: Applied spectroscopy
• 影响因子: 3.5
• 作者: Liu D

The role of beam dispersion in Raman and photo-stimulated luminescence piezo-spectroscopy of yttria-stabilized zirconia in multi-layered coatings

光束色散在多层涂层中氧化钇稳定氧化锆的拉曼和光激发光压电光谱中的作用

• DOI: 10.1016/j.actamat.2012.08.052
• 发表时间: 2013
• 期刊: Acta Materialia
• 影响因子: 9.4
• 作者: Liu D

The NiSi melting curve to 70GPa

NiSi熔化曲线至70GPa

• DOI: 10.1016/j.pepi.2014.05.005
• 发表时间: 2014
• 期刊: Physics of the Earth and Planetary Interiors
• 影响因子: 2.3
• 作者: Lord O