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EPR OF BOROHYDRIDE IRON PORPHYRIN COMPLEXES MODELS FOR REDUCTASES

EPR OF BOROHYDRIDE IRON PORPHYRIN COMPLEXES MODELS FOR REDUCTASES
还原酶硼氢化铁卟啉配合物模型的 EPR
批准号:
6120661
负责人:
KENNETH S SUSLICK
金额:
$0.27万
依托单位国家:
美国
项目类别:
财政年份:
1998
资助国家:
美国
项目状态:
已结题
起止时间:
1998-04-15 至 1999-11-30

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中文摘要
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英文摘要
In addition to catalytic oxidations, many porphyrin based enzymatic systems reduce substrates, such as in the hydrodehalogenation proteins found in bacteria. Recent chemical investigations have tried to model this reaction using iron porphyrin catalyzed borohydride reductions. We are attempting to determine the intermediates in these reactions, using EPR to elucidate both the oxidation state of the metal and the a anion radical nature of the porphyrinic macrocycle.
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EPR & STRUCTURAL STUDIES OF METALLOPORPHYRINS
  • 批准号:
    6120650
  • 项目类别:
  • 资助金额:
    $0.38万
  • 财政年份:
    1998
  • 负责人:
    KENNETH S SUSLICK
  • 依托单位:
EPR & STRUCTURAL STUDIES OF METALLOPORPHYRINS
  • 批准号:
    6251785
  • 项目类别:
  • 资助金额:
    $0.42万
  • 财政年份:
    1997
  • 负责人:
    KENNETH S SUSLICK
  • 依托单位:
EPR & STRUCTURAL STUDIES OF METALLOPORPHYRINS
  • 批准号:
    6251765
  • 项目类别:
  • 资助金额:
    $0.42万
  • 财政年份:
    1997
  • 负责人:
    KENNETH S SUSLICK
  • 依托单位:
EPR OF BOROHYDRIDE IRON PORPHYRIN COMPLEXES: MODELS FOR REDUCTASES
  • 批准号:
    6251786
  • 项目类别:
  • 资助金额:
    $0.42万
  • 财政年份:
    1997
  • 负责人:
    KENNETH S SUSLICK
  • 依托单位:
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