HIGHLY REACTIVE SPECIES CONTAINING ELECTRON DEFICIENT MAIN GROUP ATOMS

含有缺电子主族原子的高反应性物质

• 批准号: 6486694
• 负责人: PETER GASPAR
• 金额: $ 15.75万
• 依托单位: WASHINGTON UNIVERSITY
• 依托单位国家: 美国
• 财政年份: 2001
• 资助国家: 美国
• 起止时间: 2001-08-01 至 2002-07-31
• 项目状态: 已结题
• 来源: https://reporter.nih.gov/project-details/6486694
• 关键词: biological products; biomaterials; biomedical resource; spectrometry

The goals of this project are to understand the factors that control the reactions of novel electron-deficient and multiply bonded species that are heavier analogs of the reactive intermediates of organic chemistry containing second- , third- and fourth-row elements in groups 13, 14, and 15. It is hoped that by generating new novel molecules, exploring their reactions, and determining their reaction mechanisms, it will be possible to extend the powerful mechanistic ideas of organic chemistry to the prediction and rationalization of bond-making and bond-braking processes throughout the periodic table. Considerable progress has already been made. Among the highlights of the past five years has been the development of general routes for the formation of phosphinidenes, molecules containing mono-valent phosphorus atoms. Their chemistry has been explored. A triplet ground electronic state was established for mesitylphosphinidene Mes-P, the first triplet ground state of a carbene analog to have been observed.

本项目的目标是了解 新型缺电子和多键反应的控制 是活性中间体的较重类似物的物种 含有第二、第三和第四行元素的有机化学 在第13、14和15组。希望通过产生新的小说 分子，探索它们的反应，并确定它们的反应 机械，它将有可能扩展强大的机械 有机化学思想对生物多样性预测和合理化的启示 在整个元素周期表中，键的形成和键的制动过程。 已经取得了相当大的进展。其中的亮点是 过去的五年是发展铁路总路线的五年。 含单价的亚膦分子的形成 磷原子。他们的化学反应已经被探索过了。三胞胎 甲苯基膦的基态电子结构 MES-P，第一个三重基态 已经观察到一种卡宾类似物。