Bringing the 4th Dimension to Chemical Crystallography - Time Resolved Photocrystallography
将第四维引入化学晶体学——时间分辨光晶体学
基本信息
- 批准号:EP/D058147/1
- 负责人:
- 金额:$ 53.76万
- 依托单位:
- 依托单位国家:英国
- 项目类别:Research Grant
- 财政年份:2006
- 资助国家:英国
- 起止时间:2006 至 无数据
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
The importance of knowing the structure of a material to atomic resolution, the number and nature of the connectivities between the atoms, is fundamental in understanding the properties of the material. X-ray crystallography is the best method of obtaining the detailed structure of solid materials, and provides a 3D picture of the structure. However, until now, it is a technique that only looks as molecules in their ground (unreactive) state. In this proposal, for the first time, we wish to introduce the dimension of time into the crystallographic experiment. By combining the X-ray experiment with a synchronised light source, that activates the molecules into an excited (reactive) state, we will look at the structures of species with lifetimes of microseconds or even nanoseconds. To achieve this we need to build protective molecular cages around these photoreactive molecules, and to compare their solid state behaviour with what occurs in solution using time resolved IR techniques.
了解材料结构对原子分辨率的重要性,原子之间连接的数量和性质,是理解材料性质的基础。X射线晶体学是获得固体材料详细结构的最佳方法,并提供结构的3D图像。然而,到目前为止,它是一种技术,只看起来像分子在他们的地面(非反应)状态。在这个提议中,我们希望第一次将时间维度引入晶体学实验。通过将X射线实验与同步光源相结合,激活分子进入激发(反应)状态,我们将研究寿命为微秒甚至纳秒的物种结构。为了实现这一点,我们需要建立保护这些光反应分子周围的分子笼,并比较它们的固态行为与发生在溶液中使用时间分辨红外技术。
项目成果
期刊论文数量(10)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
The Supplementary Material contains additional figures of X-ray structures from Photochemistry of framework-supported M(diimine)(CO)
补充材料包含来自框架支撑的 M(二亚胺)(CO)光化学的 X 射线结构的附加图
- DOI:10.6084/m9.figshare.4236170
- 发表时间:2016
- 期刊:
- 影响因子:0
- 作者:Reade T
- 通讯作者:Reade T
Reversible 100% linkage isomerization in a single-crystal to single-crystal transformation: photocrystallographic identification of the metastable [Ni(dppe)(eta1-ONO)Cl] isomer.
- DOI:10.1002/anie.200901706
- 发表时间:2009-07
- 期刊:
- 影响因子:0
- 作者:M. Warren;S. Brayshaw;A. Johnson;S. Schiffers;P. Raithby;T. Easun;M. George;J. Warren;S. Teat
- 通讯作者:M. Warren;S. Brayshaw;A. Johnson;S. Schiffers;P. Raithby;T. Easun;M. George;J. Warren;S. Teat
Photophysics and electrochemistry of a platinum-acetylide disubstituted perylenediimide.
- DOI:10.1039/c3dt50874a
- 发表时间:2014-01
- 期刊:
- 影响因子:4
- 作者:Ben A Llewellyn;A. Slater;G. Goretzki;T.P. Sun;Xue-Zhong Davies;E. Stephen;Stephen P Lewis;W. Beeby;A. George;Michael W;A. Beeby;M. George;N. Champness
- 通讯作者:Ben A Llewellyn;A. Slater;G. Goretzki;T.P. Sun;Xue-Zhong Davies;E. Stephen;Stephen P Lewis;W. Beeby;A. George;Michael W;A. Beeby;M. George;N. Champness
Modification of coordination networks through a photoinduced charge transfer process
- DOI:10.1039/c3sc52745j
- 发表时间:2014-01-01
- 期刊:
- 影响因子:8.4
- 作者:Easun, Timothy L.;Jia, Junhua;Champness, Neil R.
- 通讯作者:Champness, Neil R.
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Neil Robert Champness其他文献
Neil Robert Champness的其他文献
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{{ truncateString('Neil Robert Champness', 18)}}的其他基金
Complex-bearing Metal-Organic Frameworks: Snapshots of Reactions
复合金属有机框架:反应快照
- 批准号:
EP/S002995/2 - 财政年份:2021
- 资助金额:
$ 53.76万 - 项目类别:
Fellowship
Complex-bearing Metal-Organic Frameworks: Snapshots of Reactions
复合金属有机框架:反应快照
- 批准号:
EP/S002995/1 - 财政年份:2019
- 资助金额:
$ 53.76万 - 项目类别:
Fellowship
Two dimensional supramolecular networks on insulators: structural organisation, fluorescence and host-guest interactions
绝缘体上的二维超分子网络:结构组织、荧光和主客体相互作用
- 批准号:
EP/N033906/1 - 财政年份:2016
- 资助金额:
$ 53.76万 - 项目类别:
Research Grant
Exotic Phases, Growth and Dynamics of Self-Assembled Molecular Networks: Random Tilings, Quasicrystals and Glasses
自组装分子网络的奇异相、生长和动态:随机平铺、准晶体和玻璃
- 批准号:
EP/K01773X/1 - 财政年份:2013
- 资助金额:
$ 53.76万 - 项目类别:
Research Grant
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