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Metal-Catalyzed Methods for Organic Synthesis

Metal-Catalyzed Methods for Organic Synthesis
金属催化有机合成方法
批准号：
9923326
负责人：
STEPHEN L BUCHWALD
金额：
$5.7万
依托单位：
MASSACHUSETTS INSTITUTE OF TECHNOLOGY
依托单位国家：
美国
项目类别：
财政年份：
2017
资助国家：
美国
项目状态：
已结题
起止时间：
2017-06-01 至 2022-05-31
来源：
https://reporter.nih.gov/project-details/9923326
关键词：
AgrochemicalsAlkenesBiologicalCarbonCatalysisComplexCopperElectronicsMetalsMethodsNatural ProductsNitrogenOrganic SynthesisPharmacologic SubstanceProcessReactionStructureTechniquesWorkbenzimidazoledesigninterestscaffoldsensor

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Project Summary/Abstract: We are interested in developing general and useful new methods for the formation of carbon- carbon and carbon-heteroatom bonds. Utilizing copper-catalysis we will focus on the direct asymmetric functionalization of benzimidazoles with unactivated olefins. Substituted benzimidazoles are ubiquitous scaffolds in pharmaceuticals, natural products, agrochemicals, electronics and sensors. New methods would allow access to quickly and efficiently build a wide-range of complex molecules. Optimization of reaction conditions, exploration of substrate scope and mechanistic studies will be conducted to aid us in the discovery and utility of this work.
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Metal-Catalyzed Methods for Organic Synthesis
Metal-Catalyzed Methods for Organic Synthesis
Metal-Catalyzed Methods for Organic Synthesis
Metal-Catalyzed Methods for Organic Synthesis
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