Non-destructive diagnosis of solid oxide fuel cell performance and degradation

固体氧化物燃料电池性能和退化的无损诊断

• 批准号: 261678-2008
• 负责人: Kesler, Olivera
• 金额: $ 1.97万
• 依托单位: University of Toronto
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2010
• 资助国家: 加拿大
• 起止时间: 2010-01-01 至 2011-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=456056
• 关键词: Non; destructive; diagnosis; solid; oxide

Solid oxide fuel cells are highly efficient energy conversion devices that produce electricity from a variety of readily available fuels with no smog-forming air pollution emissions and very low emissions of greenhouse gases. Reductions in smog would lead to a decrease in the occurrence and corresponding health care costs of respiratory diseases such as asthma, which have been demonstrated to be caused by air pollution. However, despite these potential environmental and health benefits, fuel cells remain limited in their use by insufficient reliability and durability. The proposed research program seeks to improve the lifetime and performance of solid oxide fuel cells by achieving an improved understanding of the causes of performance degradation. The research program investigates new techniques to identify the causes of performance degradation in solid oxide fuel cells. There are currently numerous causes of performance loss in fuel cells, which are difficult to distinguish from each other in standard degradation studies involving the monitoring of current density as a function of time at a given operating voltage. The proposed research program utilizes a novel combination of numerical modeling and experimental studies to non-invasively diagnose the causes of performance loss. This diagnosis is based on the identification of the various electrochemical signatures of each degradation mode, with the goal of using the knowledge gained to modify the materials and design of fuel cells in order to improve their reliability and durability. Resulting longer lifetimes and higher performances of solid oxide fuel cells will in turn lead to their more widespread use, thereby allowing Canadian society to enjoy greater benefits from their environmental and health advantages.

固体氧化物燃料电池是高效的能源转换装置，可以利用各种现成的燃料发电，不会产生烟雾形成的空气污染排放，温室气体排放也非常低。 雾霾的减少将导致哮喘等呼吸道疾病的发生率和相应的医疗费用下降，这些疾病已被证明是由空气污染引起的。 然而，尽管有这些潜在的环境和健康益处，燃料电池的使用仍然因可靠性和耐用性不足而受到限制。 拟议的研究计划旨在通过更好地了解性能下降的原因来提高固体氧化物燃料电池的寿命和性能。 该研究计划研究新技术来确定固体氧化物燃料电池性能下降的原因。 目前，导致燃料电池性能损失的原因有很多，在标准退化研究中很难区分这些原因，这些研究涉及在给定工作电压下监测电流密度随时间的变化。 拟议的研究计划利用数值建模和实验研究的新颖组合来非侵入性地诊断性能损失的原因。 该诊断基于对每种退化模式的各种电化学特征的识别，目的是利用获得的知识来修改燃料电池的材料和设计，以提高其可靠性和耐用性。 固体氧化物燃料电池的更长寿命和更高性能反过来将导致其更广泛的使用，从而使加拿大社会从其环境和健康优势中享受到更大的利益。