Ligand design for organometallic and inorganic chemistry

有机金属和无机化学的配体设计

• 批准号: 261742-2008
• 负责人: Johnson, Samuel
• 金额: $ 3.5万
• 依托单位: University of Windsor
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2010
• 资助国家: 加拿大
• 起止时间: 2010-01-01 至 2011-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=456092
• 关键词: Ligand; design; organometallic; inorganic; chemistry

Our research objectives involve the synthesis of new inorganic complexes for a variety of applications, including inert-bond activation, catalysis, and magnetism. Our approach involves the rational design of ligands capable of imparting the desired reactivity or properties to metal complexes. A variety of different ligand designs aimed at different applications will be discussed in this proposal. Our end goals include the synthesis of new transition metal catalysts, the synthesis of dinuclear or polynuclear complexes for inert-bond activation, such as C-H bond activation and functionalization, and the rational assembly of polynuclear magnetic complexes with the end goal of the assembly of larger magnetic assemblies from fully characterized building-blocks.

我们的研究目标包括合成新的无机配合物，用于各种应用，包括惰性键激活，催化和磁性。我们的方法包括合理设计配体，使其能够赋予金属配合物所需的反应性或性质。本提案将讨论针对不同应用的各种不同配体设计。我们的最终目标包括合成新的过渡金属催化剂，合成用于惰性键激活的双核或多核配合物，例如C-H键的激活和功能化，以及多核磁性配合物的合理组装，最终目标是通过完全表征的构建块组装更大的磁性组装。