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Spectroscopic investigations of electronic control of chemical reactivity

Spectroscopic investigations of electronic control of chemical reactivity
化学反应电子控制的光谱研究
批准号:
298395-2010
负责人:
Kennepohl, Pierre
金额:
$2.91万
依托单位国家:
加拿大
项目类别:
Discovery Grants Program - Individual
财政年份:
2010
资助国家:
加拿大
项目状态:
已结题
起止时间:
2010-01-01 至 2011-12-31

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中文摘要
翻译
控制化学和生物化学反应需要了解控制这些过程的基本因素。该提案旨在继续探索电子结构对无机,有机金属和生物过程中反应性的作用。具体的例子包括生物相关分子中S-N键的表征,金属-配体键合的探索,以确定静电与共价相互作用在控制反应性中的重要性和作用,以及对表现出新反应性的金属-双氧络合物的新家族的研究。
英文摘要
Control of chemical and biochemical reactions requires understanding of the fundamental factors that govern those processes. This proposal seeks to continue to explore the role of electronic structure on reactivity in inorganic, organometallic, and biological processes. Specific examples include the characterization of S-N bonds in biologically-relevant molecules, the exploration of metal-ligand bonding to determine the importance and role of electrostatic vs covalent interactions in controlling reactivity, and the investigation of a new family of metal-dioxygen complexes that exhibits novel reactivity.
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Enabling Molecular Computing: New approaches to the design and investigation of molecular junctions and quantum bits
  • 批准号:
    RGPIN-2021-02487
  • 项目类别:
    Discovery Grants Program - Individual
  • 资助金额:
    $1.75万
  • 财政年份:
    2022
  • 负责人:
    Kennepohl, Pierre
  • 依托单位:
Enabling Molecular Computing: New approaches to the design and investigation of molecular junctions and quantum bits
  • 批准号:
    RGPIN-2021-02487
  • 项目类别:
    Discovery Grants Program - Individual
  • 资助金额:
    $1.75万
  • 财政年份:
    2021
  • 负责人:
    Kennepohl, Pierre
  • 依托单位:
X-ray spectroscopy as a probe of unique bonding interactions of importance in transition metal catalytic processes
  • 批准号:
    RGPIN-2016-05453
  • 项目类别:
    Discovery Grants Program - Individual
  • 资助金额:
    $1.82万
  • 财政年份:
    2020
  • 负责人:
    Kennepohl, Pierre
  • 依托单位:
X-ray spectroscopy as a probe of unique bonding interactions of importance in transition metal catalytic processes
  • 批准号:
    RGPIN-2016-05453
  • 项目类别:
    Discovery Grants Program - Individual
  • 资助金额:
    $1.82万
  • 财政年份:
    2019
  • 负责人:
    Kennepohl, Pierre
  • 依托单位:
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