Spectroscopic investigations of electronic control of chemical reactivity

化学反应电子控制的光谱研究

• 批准号: 298395-2010
• 负责人: Kennepohl, Pierre
• 金额: $ 2.91万
• 依托单位: University of British Columbia
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2011
• 资助国家: 加拿大
• 起止时间: 2011-01-01 至 2012-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=480726
• 关键词: Spectroscopic; investigations; electronic; control; chemical

Control of chemical and biochemical reactions requires understanding of the fundamental factors that govern those processes. This proposal seeks to continue to explore the role of electronic structure on reactivity in inorganic, organometallic, and biological processes. Specific examples include the characterization of S-N bonds in biologically-relevant molecules, the exploration of metal-ligand bonding to determine the importance and role of electrostatic vs covalent interactions in controlling reactivity, and the investigation of a new family of metal-dioxygen complexes that exhibits novel reactivity.

控制化学和生化反应需要了解控制这些过程的基本因素。本提案旨在继续探索电子结构在无机，有机金属和生物过程中反应性的作用。具体的例子包括生物相关分子中S-N键的表征，金属-配体键的探索，以确定静电与共价相互作用在控制反应性中的重要性和作用，以及新型反应性金属-二氧配合物家族的研究。