Chemical origins of optical self action effects in composite media

复合介质中光学自作用效应的化学起源

• 批准号: 105953-2007
• 负责人: Andrews, Mark
• 金额: $ 2.77万
• 依托单位: McGill University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2011
• 资助国家: 加拿大
• 起止时间: 2011-01-01 至 2012-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=475392
• 关键词: Chemical; origins; optical; self; action

When a laser beam guides in a solid medium the light spreads out (diffracts) over distance. In some cases, the diffraction effect is counteracted when the intensity of light acts to alter the refractive index of the medium. In this case, the beam might act on itself (optical self-action) to counteract the effect of diffraction. If the optical self-action exactly balances diffraction we have have self-focusing and the wave creates its own waveguide to give something called a spatial soliton. Solitons like these are of interest to optical comunications because they can travel over long distances without the need of amplification or correction. In some media, like certain organic polymers and photosensitive glasses, soliton-like behaviour is observed. The difference is that the waveguide that is created is permanent. This research program seeks to understand the physical and chemical processes behind Light Induced Self Inscription (LISI) in media that exhibit a permanent refractive index change. The idea is to carefully describe the underlying photochemistry that supports permanent self-writing. Over the term of this grant, the author will explore LISI in polymers, polymer composites, "molecular silica" cage-polymer composites and hybrid organic-inorganic glasses. The research will have impact on our understanding of the origins of the phenomenon and how it might be used to make optical integrated circuit devices.

当激光束在固体介质中导引时，光在距离上扩散(衍射)。在某些情况下，当光的强度改变介质的折射率时，衍射效应被抵消。在这种情况下，光束可能作用于自身(光学自身作用)，以抵消衍射的影响。如果光学自身作用精确地平衡了衍射，我们就有了自聚焦，波就产生了自己的波导，从而产生了一种称为空间孤子的东西。光通信对这种孤子很感兴趣，因为它们可以在不需要放大或校正的情况下远距离传输。在某些介质中，如某些有机聚合物和光敏玻璃中，观察到了类孤子行为。不同之处在于，产生的波导是永久性的。这项研究计划试图了解光诱导自刻(LISI)在表现出永久折射率变化的介质中背后的物理和化学过程。这个想法是为了仔细描述支持永久自我写作的潜在光化学。在这笔赠款的期限内，作者将在聚合物、聚合物复合材料、“分子二氧化硅”笼状聚合物复合材料和有机-无机混合玻璃方面探索LISI。这项研究将对我们理解这种现象的起源以及如何将其用于制造光学集成电路器件产生影响。