Studies of Group 15 complexes of the Lanthanoids and Group 2 metals-An unexploited field of research

镧系元素和第 2 族金属的第 15 族配合物的研究——一个尚未开发的研究领域

• 批准号: ARC : DP0211090
• 负责人: Dr Peter Junk
• 金额: $ 20.21万
• 依托单位: James Cook University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2002
• 资助国家: 澳大利亚
• 起止时间: 2002-01-01 至 2004-12-31
• 项目状态: 已结题
• 来源: https://researchdata.edu.au/studies-group-15-field-research/66422
• 关键词: Studies; Group; 15; complexes; Lanthanoids

Studies of Group 15 complexes of the Lanthanoids and Group 2 metals-An unexploited field of research. The project will initially explore new amido chemisty of the lanthanoids. This chemistry will develop towards complexes with lanthanoid-or Group 2-phosphorus, -arsenic, -antimony or -bismuth connectivities. This chemistry is surprisingly underdeveloped given the wealth of applications found for oxo and amido complexes of the same metals. Structural studies involving the complexes using cutting edge ligands will reveal interesting coordination modes. The discovery of new reaction pathways will be of interest to the wider chemical community. The chemical reactivity and potential catalytic or luminescent properties of these compounds will be studied and will result in publications in international journals.

第15族镧系元素与第2族金属配合物的研究--一个尚未开发的研究领域。该项目将首先探索镧系元素的新酰胺化学。这种化学将向具有镧系元素或第2族-磷、-砷、-锑或-铋连接性的络合物发展。这种化学是令人惊讶的欠发达，鉴于丰富的应用发现的氧代和酰胺络合物的相同的金属。涉及使用尖端配体的配合物的结构研究将揭示有趣的协调模式。新反应途径的发现将引起更广泛的化学界的兴趣。将研究这些化合物的化学反应性和潜在的催化或发光特性，并将在国际期刊上发表论文。