Redox-active ligands and their metal complexes

氧化还原活性配体及其金属配合物

• 批准号: 194218-2009
• 负责人: Hicks, Robin
• 金额: $ 4.37万
• 依托单位: University of Victoria
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2012
• 资助国家: 加拿大
• 起止时间: 2012-01-01 至 2013-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=514010
• 关键词: Redox; active; ligands; their; metal

Whereas many important physical and chemical properties of transition metal complexes stem from metal-centered redox activity/chemistry, coordinated ligands may also be active electron-transfer participants. Complexes of so-called redox active ligands (RALs) have been known for over 40 years but research on RAL complexes has been limited in scope and focused heavily on electronic structure elucidation. But in the past few years new kinds of RALs have been discovered and there have been reports of novel reactivity/catalysis using RAL complexes.

虽然过渡金属络合物的许多重要物理和化学性质源于金属中心的氧化还原活性/化学，但配位配体也可以是活性电子转移参与者。 所谓的氧化还原活性配体（RALs）的络合物已经已知超过40年，但是对RAL络合物的研究在范围上受到限制，并且主要集中在电子结构解析上。但是在过去的几年中，已经发现了新种类的RAL，并且已经报道了使用RAL络合物的新的反应性/催化。