Plasmonic structures and their applications in nanoelectrochemistry and single-molecule spectroelectrochemistry

等离子体结构及其在纳米电化学和单分子光谱电化学中的应用

• 批准号: 238407-2009
• 负责人: Brolo, Alexandre
• 金额: $ 4.37万
• 依托单位: University of Victoria
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2012
• 资助国家: 加拿大
• 起止时间: 2012-01-01 至 2013-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=514362
• 关键词: Plasmonic; structures; their; applications; nanoelectrochemistry

Our research program is centered on the development of metallic nanostructures and their applications in surface-enhanced phenomena, chemical sensing and spectroelectrochemistry (SEC). We are particularly interested in nanostructures that support surface plasmon (SP) excitations (either localized or propagating SPs) in the visible range (plasmonic structures). Recently, we have achieved the following important breakthroughs in plasmonics that will culminate in the development of new approaches for single-molecule spectroelectrochemistry (SM-SEC) and nanoelectrochemistry: 1) We observed single-molecule surface-enhanced Raman scattering (SM-SERS) from dyes adsorbed on an electrode surface and were able to control the single-molecule dynamics by changing the applied potential; 2) We demonstrated that nanoholes in metal films are sensitive to adsorption and support enhanced spectroscopy. We propose to capitalize on these breakthroughs by further extending the application of SM-SEC to redox systems and protein adsorption. We will also use the concept of "in-hole" sensing to study the electrochemistry of species inside the nanoholes. The optical properties of the nanoholes will depend on the oxidation state of the adsorbed molecules, which will be the basis for the SEC from the nanohole structures. Surface-enhanced SEC using shaped nanoholes will also be explored.

我们的研究项目集中在金属纳米结构的发展及其在表面增强现象，化学传感和光谱电化学（SEC）中的应用。我们特别感兴趣的纳米结构，支持表面等离子体（SP）激发（无论是本地或传播SP）在可见光范围内（等离子体结构）。近年来，我们在等离子体激元学领域取得了以下重要突破，这些突破将为单分子光谱电化学（SM-SEC）和纳米电化学的发展提供新的途径：1）我们观察到吸附在电极表面的染料的单分子表面增强拉曼散射（SM-SERS），并能够通过改变外加电位来控制单分子动力学; 2）我们证明了金属薄膜中的纳米孔对吸附和支持增强光谱敏感。我们建议利用这些突破，进一步扩大应用SM-SEC的氧化还原系统和蛋白质吸附。我们也将使用“孔内”感测的概念来研究纳米孔内物种的电化学。纳米孔的光学性质将取决于吸附分子的氧化态，这将是从纳米孔结构进行SEC的基础。还将探索使用成形纳米孔的表面增强SEC。