Microstructure in hydrogen induced cracking of pipeline steel

管线钢氢致开裂的显微组织

• 批准号: 433803-2012
• 负责人: Szpunar, Jerzy
• 金额: $ 3.89万
• 依托单位: University of Saskatchewan
• 依托单位国家: 加拿大
• 项目类别: Collaborative Research and Development Grants
• 财政年份: 2014
• 资助国家: 加拿大
• 起止时间: 2014-01-01 至 2015-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=552651
• 关键词: Microstructure; hydrogen; induced; cracking; pipeline

One of the most important damage modes in oil and gas pipeline steels is Hydrogen Induced Cracking (HIC) that is often associated with sulfide stress cracking SSC. This type of failure dominates in environment of hydrogen sulfide that is present in the natural gas and fluids transported in the pipe. HIC has been studied extensively, however the mechanisms of failure related to presence of sulfides and other nonmetallic inclusions is not yet sufficiently clear. The presence of hydrogen sulphide in natural gas and oil has lead to renew interest in development of steels that are more resistant to HIC and SSR related failure. In the proposed program, a detailed investigation of HIC will be carried on X-60 and X-65 pipeline steels manufactured by Evraz. The objective of the present project is to study the influence of microstructure of the steels on hydrogen ingress and distribution to establish a role that phases, precipitates, texture, grain interfaces play in HIC and SSC in the environment of stress and corrosion. The obtained results would help in identifying the steel structure that will improve the resistance to failure in sour gas and oil environment. The knowledge gained from the experiments will be used to build up microstructure based model that can help in predicting the hydrogen-induced failure behavior of steels. Novel methods of structural analysis by in situ orientation imaging under stress, mapping of phase composition, grain orientation, stress distribution, chemical composition and using hydrogen microprint to image hydrogen distribution in steels are expected to provide novel information that are relevant for understanding of the processes of nucleation and propagation of cracks. Synchrotron three-dimensional imaging of cracks propagation might offer new understanding of fracture process in hydrogen and sulfide environment. The results obtained will allow EVRAZ to consider modification of the manufacturing processes and to adopt strategy to mitigate HIC in pipeline steels this company produces.

油气管道钢中最重要的损伤模式之一是氢致开裂（HIC），它通常与硫化物应力开裂（SSC）有关。这种类型的故障主要发生在天然气和管道中输送的流体中存在硫化氢的环境中。HIC已经得到了广泛的研究，但是与硫化物和其他非金属夹杂物的存在有关的失效机制还不够清楚。天然气和石油中硫化氢的存在重新引起了人们对开发更能抵抗HIC和SSR相关故障的钢的兴趣。在拟议的计划中，将对Evraz生产的X-60和X-65管道钢进行详细的HIC调查。本项目的目的是研究钢的微观组织对氢进入和分布的影响，以确定相、析出物、织构、晶粒界面在应力和腐蚀环境下HIC和SSC中的作用。所得结果有助于识别钢结构，提高钢结构在含酸气和含油环境下的抗破坏能力。从实验中获得的知识将用于建立基于微观结构的模型，该模型有助于预测钢的氢致失效行为。新的结构分析方法包括应力下的原位取向成像、相组成、晶粒取向、应力分布、化学成分的绘制以及使用氢显微打印技术对钢中的氢分布进行成像，这些方法有望为理解裂纹的成核和扩展过程提供新的信息。裂纹扩展的同步加速器三维成像可能为氢硫化物环境下的断裂过程提供新的认识。获得的结果将允许EVRAZ考虑修改制造工艺，并采取策略来减少该公司生产的管道钢中的HIC。