Nanoscience under extreme forces

极端力量下的纳米科学

• 批准号: 6594-2013
• 负责人: Kreuzer, Juergen
• 金额: $ 3.21万
• 依托单位: Dalhousie University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2015
• 资助国家: 加拿大
• 起止时间: 2015-01-01 至 2016-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=568476
• 关键词: Nanoscience; under; extreme; forces

At the atomic level matter can be modified by the application of large forces in particular by large external electrostatic fields. In such fields chemical effects come into play because the electronic orbitals get distorted to such a degree that the chemical characteristics of an atom or molecule become altered. In this way, new pathways in chemical reactions may be established. Examples of technological relevance are field evaporation in the field ion microscope that is used in Atom Probe Tomography (APT) to map the composition of an alloy atom by atom and layer by layer. The quantum mechanical theory of field evaporation of metals was developed in the late 1980s by my group and others. Recently it has become of interest to use ATP for the study of oxides. However, as an expert in the field, Bernard Deconihout, recently stated "Although APT has provided a large number of results on a wide panel of materials, interpretation of 3D images are sometimes difficult due to a lack in the understanding of the different evaporation mechanisms involved in semiconductors and oxides". We will make a systematic study of APT for insulators, in particular oxides. The benefits to APT will be substantial as our recent pilot project on MgO already showed. Extreme forces in nanoscience are also found in confined geometries such as polymer films under high pressure and proton wires in membrane pores. The interest for such a study in biology on the one hand and in paint coatings as well should be followed up. Extreme forces are also needed to break and make bonds is the attachment and detachment of cells in blood vessels and stents by hydrodynamic shear forces relevant to biology, medicine, and biofouling of ships.

在原子水平上，物质可以通过施加大的力，特别是通过大的外部静电场来改变。在这样的领域中，化学效应开始发挥作用，因为电子轨道被扭曲到一定程度，原子或分子的化学特性被改变。通过这种方式，可以建立化学反应中的新途径。技术相关性的例子是场离子显微镜中的场蒸发，场离子显微镜用于原子探针断层扫描（APT），以逐原子和逐层绘制合金的成分。金属场蒸发的量子力学理论是在20世纪80年代后期由我的团队和其他人发展起来的。近年来，利用ATP研究氧化物已引起人们的兴趣。然而，该领域的专家Bernard Deconihout最近表示：“尽管APT在广泛的材料面板上提供了大量结果，但由于缺乏对半导体和氧化物中所涉及的不同蒸发机制的理解，有时很难解释3D图像。我们将系统地研究APT用于绝缘体，特别是氧化物。APT的好处将是巨大的，因为我们最近的MgO试点项目已经显示。 纳米科学中的极端力也存在于受限的几何形状中，例如高压下的聚合物膜和膜孔中的质子线。应继续关注对生物学和油漆涂层进行此类研究的兴趣。 还需要极端的力来破坏和形成结合是血管和支架中的细胞通过与生物学、医学和船舶生物污染相关的流体动力学剪切力的附着和分离。