Plasma synthesis of reactive species and nanoparticles with controlled surface chemistry

具有受控表面化学的活性物质和纳米粒子的等离子体合成

• 批准号: 250354-2012
• 负责人: Coulombe, Sylvain
• 金额: $ 2.99万
• 依托单位: McGill University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2015
• 资助国家: 加拿大
• 起止时间: 2015-01-01 至 2016-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=570900
• 关键词: Plasma; synthesis; reactive; species; nanoparticles

Nanoparticles are physicochemical entities having at least one dimension inferior to 100 nm. Due to their extremely high surface areas, such particles are ideal hosts for chemical reactions and gas storage through adsorption on their surface. They can be fabricated of numerous materials including metals, semiconductors and insulators and used in a variety of applications ranging from catalysis, photovoltaic cells, and fuel additives in rocket engines. When properly stabilized and dispersed in a host fluid, they may form colloidal suspensions. The nanofluids thus produced exhibit enhanced or new properties with respect to the base fluids. Nanoparticles may render electrically conductive an otherwise insulating fluid. Their composition can be tuned to acquire uncommon properties like efficient direct solar energy absorbance, enhanced heat capacity (storage capacity), laser light amplification and chemical affinity with specific molecules. One of the main objectives of this research programme is to further develop various plasma-assisted synthesis processes to obtain the desired nanoparticles and nanofluids. Specific applications in mass transfer, gas storage and solar energy harvesting and conversion will be considered. Miniature high-pressure cold plasma jets are the subject of intense research and development. Plasma jets of size in the 1-20 mm range and capable of efficiently produce and transport reactive species at atmospheric pressure and above are sought for applications in a vast and rapidly growing range of fields, including plasma medicine and plasma-assisted combustion. We will investigate two particularly important aspects of cold plasma jet generation at high pressures: 1) How to design a plasma jet device which more efficiently produces and transports the species of interest to the remote surface; 2) How to design a plasma jet device to operate at pressures exceeding atmospheric. We will target applications in the synthesis and transport of NO to biological surfaces, and the OH radicals in plasma-assisted combustion.

纳米颗粒是具有至少一个小于100 nm的尺寸的物理化学实体。由于其极高的表面积，这些颗粒是化学反应和通过其表面上的吸附进行气体储存的理想宿主。它们可以由多种材料制成，包括金属，半导体和绝缘体，并用于催化，光伏电池和火箭发动机燃料添加剂等各种应用。当适当地稳定和分散在宿主流体中时，它们可以形成胶体悬浮液。由此产生的纳米流体相对于基础流体表现出增强的或新的性质。纳米颗粒可以使导电的流体具有其他绝缘性。它们的组成可以调整，以获得不寻常的性能，如有效的直接太阳能吸收，增强的热容量（存储能力），激光放大和与特定分子的化学亲和力。该研究计划的主要目标之一是进一步开发各种等离子体辅助合成工艺，以获得所需的纳米颗粒和纳米流体。将考虑质量传递、气体储存以及太阳能收集和转换方面的具体应用。 微型高压冷等离子体射流是研究和开发的热门课题。在包括等离子体医学和等离子体辅助燃烧在内的广泛且快速增长的领域中，寻求尺寸在1-20 mm范围内并且能够在大气压和更高压力下有效地产生和输送反应性物质的等离子体射流。我们将研究在高压下产生冷等离子体射流的两个特别重要的方面：1）如何设计更有效地产生感兴趣的物质并将其输送到远程表面的等离子体射流装置; 2）如何设计在超过大气压的压力下操作的等离子体射流装置。我们的目标是在合成和运输NO生物表面的应用，以及等离子体辅助燃烧中的OH自由基。