Technology for clean and scalable synthesis of metal-organic frameworks
金属有机框架的清洁和可扩展合成技术
基本信息
- 批准号:485231-2015
- 负责人:
- 金额:$ 9.08万
- 依托单位:
- 依托单位国家:加拿大
- 项目类别:Idea to Innovation
- 财政年份:2015
- 资助国家:加拿大
- 起止时间:2015-01-01 至 2016-12-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
The proposed application aims to scale up a recently-developed new and clean technology (US 62/119,436) for gram-scale manufacturing of microporous metal-organic frameworks (MOFs) into a >10 kilogram/day batch process for manufacturing multiple types of MOFs. This proven clean manufacturing process will provide a foundation to establish and incorporate a start-up company, called Q-MOF, which will be the first to commercially provide sophisticated and inexpensive MOFs for applications in academic research, as well as commercial opportunities in gas purification, hydrogen fuel cells, storage of methane and acetylene, carbon dioxide sequestration, and catalysis. Although a small number of manufacturers have recently begun commercially offering a very limited number of MOFs, these materials are available only at exorbitant cost (>$12,000 per kg). As well, the existing processes through which these materials are made are characterized by high environmental impact and safety risks, and involve corrosive starting materials and harsh reaction conditions. Our recently patented technology allows for the inexpensive, simple and environmentally-friendly synthesis of a wide diversity of MOFs from well-known and safe reagents. The proposed research, which will allow us to scale-up our clean and inexpensive MOF manufacturing technology and expand the portfolio of accessible MOF products, will enable us to establish a MOF manufacturing company that will meet the needs of the emerging research and industrial applications markets by providing large amounts (10-100kg) of MOF products for a price that is 50% or less than what is currently offered.Our initial expected market is adsorbents, with a focus on fuel cell technology, but we also aim to provide products to research users with a variety of applications.
所提出的申请旨在将最近开发的用于微孔金属有机框架(M0 F)的克级制造的新的清洁技术(US 62/119,436)按比例扩大到用于制造多种类型的M0 F的>10千克/天的分批工艺。这种经过验证的清洁制造工艺将为建立和合并一家名为Q-MOF的初创公司提供基础,该公司将成为第一家在商业上为学术研究应用提供复杂且廉价的MOF的公司,以及气体净化,氢燃料电池,甲烷和乙炔储存,二氧化碳封存和催化的商业机会。虽然少数制造商最近开始商业化地提供数量非常有限的MOFs,但这些材料的价格很高(每公斤> 12,000美元)。此外,制造这些材料的现有方法的特征在于高环境影响和安全风险,并且涉及腐蚀性起始材料和苛刻的反应条件。我们最近获得专利的技术允许使用已知且安全的试剂廉价、简单且环保地合成多种MOF。这项拟议中的研究将使我们能够扩大清洁和廉价的MOF制造技术,并扩大可获得的MOF产品组合,将使我们能够建立一个MOF制造公司,通过提供大量的产品,满足新兴的研究和工业应用市场的需求。(10- 100 kg)的MOF产品,价格是目前的50%或更低。我们最初的预期市场是吸附剂,重点是燃料电池技术,但我们也旨在为研究用户提供具有各种应用的产品。
项目成果
期刊论文数量(0)
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Friscic, Tomislav其他文献
Cocrystal architecture and properties: design and building of chiral and racemic structures by solid-solid reactions
- DOI:
10.1039/b616399h - 发表时间:
2007-01-01 - 期刊:
- 影响因子:3.4
- 作者:
Friscic, Tomislav;Jones, William - 通讯作者:
Jones, William
Oxidative Mechanochemistry: Direct, Room-Temperature, Solvent-Free Conversion of Palladium and Gold Metals into Soluble Salts and Coordination Complexes
- DOI:
10.1002/anie.201712602 - 发表时间:
2018-03-01 - 期刊:
- 影响因子:16.6
- 作者:
Do, Jean-Louis;Tan, Davin;Friscic, Tomislav - 通讯作者:
Friscic, Tomislav
Ion- and Liquid-Assisted Grinding: Improved Mechanochemical Synthesis of Metal-Organic Frameworks Reveals Salt Inclusion and Anion Templating
- DOI:
10.1002/anie.200906583 - 发表时间:
2010-01-01 - 期刊:
- 影响因子:16.6
- 作者:
Friscic, Tomislav;Reid, David G.;Duer, Melinda J. - 通讯作者:
Duer, Melinda J.
Improving Mechanical Properties of Crystalline Solids by Cocrystal Formation: New Compressible Forms of Paracetamol
- DOI:
10.1002/adma.200900533 - 发表时间:
2009-10-19 - 期刊:
- 影响因子:29.4
- 作者:
Karki, Shyam;Friscic, Tomislav;Jones, William - 通讯作者:
Jones, William
Terahertz time-domain spectroscopy and the quantitativemonitoring of mechanochemical cocrystal formation
- DOI:
10.1038/nmat1848 - 发表时间:
2007-03-01 - 期刊:
- 影响因子:41.2
- 作者:
Nguyen, K. Lien;Friscic, Tomislav;Jones, William - 通讯作者:
Jones, William
Friscic, Tomislav的其他文献
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{{ truncateString('Friscic, Tomislav', 18)}}的其他基金
Mechanochemistry and Solid-state Chemistry
机械化学和固态化学
- 批准号:
CRC-2020-00342 - 财政年份:2022
- 资助金额:
$ 9.08万 - 项目类别:
Canada Research Chairs
Nominated for the NSERC John C. Polanyi Award
获得 NSERC 约翰·波兰尼奖提名
- 批准号:
562908-2022 - 财政年份:2021
- 资助金额:
$ 9.08万 - 项目类别:
John C. Polanyi Award
Mechanochemistry And Solid-State Chemistry
机械化学和固态化学
- 批准号:
CRC-2020-00342 - 财政年份:2021
- 资助金额:
$ 9.08万 - 项目类别:
Canada Research Chairs
The development and mechanistic understanding of solid-state reactivity for energy- and materials-efficient synthesis
用于能源和材料高效合成的固态反应的发展和机理理解
- 批准号:
RGPIN-2017-06467 - 财政年份:2021
- 资助金额:
$ 9.08万 - 项目类别:
Discovery Grants Program - Individual
The development and mechanistic understanding of solid-state reactivity for energy- and materials-efficient synthesis
用于能源和材料高效合成的固态反应的发展和机理理解
- 批准号:
RGPIN-2017-06467 - 财政年份:2020
- 资助金额:
$ 9.08万 - 项目类别:
Discovery Grants Program - Individual
The development and mechanistic understanding of solid-state reactivity for energy- and materials-efficient synthesis
用于能源和材料高效合成的固态反应的发展和机理理解
- 批准号:
507837-2017 - 财政年份:2020
- 资助金额:
$ 9.08万 - 项目类别:
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Mechanochemistry and Solid-state Chemistry
机械化学和固态化学
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1000233210-2019 - 财政年份:2020
- 资助金额:
$ 9.08万 - 项目类别:
Canada Research Chairs
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用于能源和材料高效合成的固态反应的发展和机理理解
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507837-2017 - 财政年份:2019
- 资助金额:
$ 9.08万 - 项目类别:
Discovery Grants Program - Accelerator Supplements
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用于能源和材料高效合成的固态反应的发展和机理理解
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RGPIN-2017-06467 - 财政年份:2019
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$ 9.08万 - 项目类别:
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环保药物合成
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