Electrodeposition of polymer based coatings for the corrosion inhibition of 420 stainless steel

用于抑制 420 不锈钢腐蚀的聚合物基涂层的电沉积

• 批准号: 533326-2018
• 负责人: Zhitomirsky, Igor
• 金额: $ 1.82万
• 依托单位: McMaster University
• 依托单位国家: 加拿大
• 项目类别: Engage Grants Program
• 财政年份: 2018
• 资助国家: 加拿大
• 起止时间: 2018-01-01 至 2019-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=669823
• 关键词: Electrodeposition; polymer; based; coatings; corrosion

The objective of this work is the development of advanced polymer coatings by electropolymerization and**electrophoretic deposition methods for corrosion protection of injection molds. This project will be focused on**active collaboration of Husky Injection Molding Systems Ltd. and McMaster University. Husky is working on**the development of advanced injection molding equipment with improved corrosion protection. Husky is**interested in the solving of a problem of pitting corrosion of stainless steel injection molds, causing corrosion**induced fractures. This problem results in extensive damage and expensive machine downtime. McMaster**University offers a promising approach to address this problem, which is based on the use of advanced polymer**coating technologies for protection of stainless steel. The research will be focused on the application of**electropolymerization and electrophoretic deposition methods for the fabrication of polymer coatings on**stainless steel injection molds. McMaster University has developed advanced dopants and charge transfer**mediators for the electrodeposition of polypyrrole coatings on non-noble substrates by anodic**electropolymerization. The use of advanced dopants and charge transfer mediators allows**electropolymerization at reduced anodic potential and formation of adherent coatings. Another approach will**be based on the cataphoretic deposition of polyetheretherketone on stainless steel. It is based on the use of**advanced charging and dispersing agents, developed at McMaster University. Corrosion testing of stainless**steel samples and full scale mold parts will provide an insight into the influence of polymers, deposition**methods, deposition parameters, bath formulations and coating microstructures on coating adhesion and**corrosion protection. The development of advanced coatings meets the interests of Canadian industry in**advanced molding equipment, film deposition technologies and corrosion protection. The benefits of this**project will include the generation of new technological solutions, technology transfer to Husky and HQP**training. The resolution of the problem will result in job growth at Husky and increased revenue.

这项工作的目标是通过电聚合和**电泳沉积方法开发先进的聚合物涂料，用于注塑模具的防腐。该项目将专注于**赫斯基注塑系统有限公司和麦克马斯特大学的积极合作。赫斯基正在致力于**开发具有更好防腐性能的先进注塑设备。赫斯基对解决不锈钢注射模具的点蚀问题感兴趣，这会导致腐蚀**导致的破裂。该问题会造成广泛的损坏和昂贵的机器停机时间。麦克马斯特大学提供了一种解决这一问题的有希望的方法，该方法基于使用先进的聚合物**涂层技术来保护不锈钢。这项研究将集中在**电聚合和电泳沉积方法在**不锈钢注射模具上制造聚合物涂层方面的应用。麦克马斯特大学开发了先进的掺杂剂和电荷转移**介体，用于通过阳极**电聚合在非贵金属基板上电沉积聚吡咯涂层。通过使用先进的掺杂剂和电荷转移介质，可以**在降低阳极电位的情况下进行电聚合，并形成附着力涂层。另一种方法将**基于聚醚醚酮在不锈钢上的闪蒸沉积。它基于麦克马斯特大学开发的**高级充电和分散剂的使用。不锈钢样品和全尺寸模具零件的腐蚀测试将深入了解聚合物、沉积方法、沉积参数、镀液配方和涂层微观结构对涂层附着力和**腐蚀保护的影响。先进涂料的开发符合加拿大工业在**先进成型设备、薄膜沉积技术和防腐方面的兴趣。这个**项目的好处将包括产生新的技术解决方案，向赫斯基转让技术和HQP**培训。问题的解决将导致赫斯基的就业增长和收入增加。