共轭有机分子是当前有机化学、材料科学和信息科学的重要研究热点之一，碗烯是一种曲面大共轭芳香体系，具有丰富的物理化学性质，因此研究碗烯对发展新型功能材料和分子器件具有重要意义。然而有关碗烯组装的研究非常滞后，主要是缺少有效的碗烯组装基元，针对这一现状，本项目拟设计在碗烯分子的外围引入多个功能团，建立高效功能化碗烯的方法，发展多种基于碗烯分子的组装基元，并研究其组装过程中内在的物理化学性质，重点研究碗烯特有的弯曲共轭面间的相互作用、堆积以及对组装材料性质的影响，开发具有光电特性的共轭功能组装体系。

Conjugate organic molecules are interested topics for organic chemistry, material sciences and information sciences. Corrannulene is one of large conjugated molecules with bowl shape. The research on corannulene is crucial for developing functional materials and molecular devices due to its intrigued properties. However, investigations about the self-assembly of corannulenes are still in infancy due to lack of efficient self-assembled condons. In this project, we will design and synthesize several self-assembled condons based on corannulenes with multiple functional groups at the periphery of corannulene. The self-assembly of these molecules will be investigated. The studies on the effect of the curved plane of corannulenes on the convex-concave interaction and the properties of materials will also be carried out. We hope to obtain functional assembled materials with intrigued photo/electric properties.